Ga(III)-catalyzed intramolecular alkyne aminophosphorylation to 3-phosphoindoles
文献类型：期刊论文
| 作者 | Wu, Chenglin2,3; Peng, Yiqing2; Sheng, Zhe2; Ma, Rui2; Zhai, Jiajia2; Li, Jiaqi2; Pu, Jingjing2; Gu, Jiawen2; Chen, Shen2; Chen, Tianhao2 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2026 |
| 卷号 | 453页码:8 |
| 关键词 | Gallium Intramolecular addition Aminophosphorylation N -P bond Alkyne |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2025.116504 |
| 通讯作者 | Wu, Chenglin(wucl@sumhs.edu.cn) ; Shen, Hongyan(hyshen@simm.ac.cn) ; Lu, Xiuhong(luxh@sumhs.edu.cn) ; Xu, Yixin(xuyx@sumhs.edu.cn) |
| 英文摘要 | The addition of N-P bonds to alkyne remains an unsolved challenge. Herein, a gallium(III)-catalyzed intramolecular addition of N-P bond to alkyne is described. This study develops a unique Ga-catalyzed aminophosphorylation of C-C pi bonds by P-N sigma bonds, which gives a series of 3-phosphoindoles in good yields and good functional group compatibility. We also highlight that this approach creates an atom-economical platform for C-P bond formation. |
| WOS关键词 | NICKEL-CATALYZED ADDITION ; ARYL-PHOSPHO-INDOLE ; INTERNAL ALKYNES ; SIGMA-BONDS ; C-N ; PALLADIUM ; CARBOALKOXYLATION ; AMINOBORATION ; PHOSPHORYLATION ; ANNULATION |
| 资助项目 | National Natural Science Foundation of China[22107125] ; Shanghai Key Laboratory of Molecular Imaging[18DZ2260400] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001608351000007 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/319817]  |
| 专题 | 中国科学院上海药物研究所 |
| 通讯作者 | Wu, Chenglin; Shen, Hongyan; Lu, Xiuhong; Xu, Yixin |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, 555 ZuChongzhi Rd, Shanghai 201203, Peoples R China 2.Shanghai Univ Med & Hlth Sci, Sch Pharm, 279 Zhouzhu Rd,Pudong New Area, Shanghai 201318, Peoples R China 3.Shanghai Univ Med & Hlth Sci, Mental Hlth Ctr, Shanghai 200093, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Chenglin,Peng, Yiqing,Sheng, Zhe,et al. Ga(III)-catalyzed intramolecular alkyne aminophosphorylation to 3-phosphoindoles[J]. JOURNAL OF CATALYSIS,2026,453:8. |
| APA | Wu, Chenglin.,Peng, Yiqing.,Sheng, Zhe.,Ma, Rui.,Zhai, Jiajia.,...&Xu, Yixin.(2026).Ga(III)-catalyzed intramolecular alkyne aminophosphorylation to 3-phosphoindoles.JOURNAL OF CATALYSIS,453,8. |
| MLA | Wu, Chenglin,et al."Ga(III)-catalyzed intramolecular alkyne aminophosphorylation to 3-phosphoindoles".JOURNAL OF CATALYSIS 453(2026):8. |
入库方式： OAI收割
来源：上海药物研究所
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