Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units
文献类型：期刊论文
| 作者 | Shi Yunjing; Pan Shilie ; Dong Xiaoyu; Wang Ying; Zhang Min; Zhang Fangfang; Zhou Zhongxiang
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| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 51期号:20页码:10870-10875 |
| ISSN号 | 0020-1669 |
| 通讯作者 | Pan, SL |
| 中文摘要 | A new noncentrosymmetric borophosphate, Na3Cd3B(PO4)(4), has been successfully synthesized by conventional solid state reaction for the first time. It crystallizes in the orthorhombic space group Pmc2(1) with unit cell parameters of a = 13.6854(3) angstrom, b = 5.3346(11) angstrom, c = 18.2169(4) angstrom, and Z = 4. Na3Cd3B(PO4)(4) features zero-dimensional B(PO4)(4)(9-) anion units with Cd2+ and Na+/Cd2+ cations located around them, in which the BO4 tetrahedron is surrounded by four PO4 tetrahedra by sharing the vertexes of O atoms. Second harmonic generation (SHG) measurements show that Na3Cd3B(PO4)(4) exhibits a SHG response 1.1 times larger than that of KH2PO4 (KDP) and is phase matchable. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; "One Hundred Talents Project Foundation Program" of Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 201116143 |
| 公开日期 | 2013-11-07 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/2762]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi Yunjing,Pan Shilie,Dong Xiaoyu,et al. Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units[J]. INORGANIC CHEMISTRY,2012,51(20):10870-10875. |
| APA | Shi Yunjing.,Pan Shilie.,Dong Xiaoyu.,Wang Ying.,Zhang Min.,...&Zhou Zhongxiang.(2012).Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units.INORGANIC CHEMISTRY,51(20),10870-10875. |
| MLA | Shi Yunjing,et al."Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units".INORGANIC CHEMISTRY 51.20(2012):10870-10875. |
入库方式： OAI收割
来源：新疆理化技术研究所
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