New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles
文献类型：期刊论文
| 作者 | Yu, HW (Yu, Hongwei); Wu, HP (Wu, Hongping); Pan, SL (Pan, Shilie) ; Wang, Y (Wang, Ying); Yang, ZH (Yang, Zhihua); Su, X (Su, Xin)
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| 刊名 | Inorganic Chemistry
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| 出版日期 | 2013 |
| 卷号 | 52期号:9页码:5359-5365 |
| ISSN号 | 0020-1669 |
| 通讯作者 | Pan，SL |
| 中文摘要 | Introduction of the coplanar BO3 triangles in the alkali metal and alkaline-earth metal mixed fluoborate generates a new UV nonlinear optical material [Li3Ca9(BO3)(7)]center dot 2[LiF] (LCBF), which possesses a moderate SHG response as large as that of the KDP and a wide transparent region with a UV cutoff edge at 230 nm. The first-principle theoretical calculation suggests that LCBF has a relatively large birefringence (0.07; 532 nm). These properties make it a potential UV nonlinear optical material. And interestingly, LCBF is a salt-inclusion borate with the Li-F chains residing in the one-dimensional open framework, which caters to the development of the salt-inclusion compound in borate. |
| 收录类别 | SCI |
| 资助信息 | National Key Basic Research Program of China ；National Natural Science Foundation of China ；Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences |
| 公开日期 | 2013-11-05 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/2552]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, HW ,Wu, HP ,Pan, SL ,et al. New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles[J]. Inorganic Chemistry,2013,52(9):5359-5365 . |
| APA | Yu, HW ,Wu, HP ,Pan, SL ,Wang, Y ,Yang, ZH ,&Su, X .(2013).New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles.Inorganic Chemistry,52(9),5359-5365 . |
| MLA | Yu, HW ,et al."New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles".Inorganic Chemistry 52.9(2013):5359-5365 . |
入库方式： OAI收割
来源：新疆理化技术研究所
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