Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3
文献类型：期刊论文
| 作者 | Yu, HW (Yu, Hongwei); Pan, SL (Pan, Shilie) ; Wu, HP (Wu, Hongping); Yang, ZH (Yang, Zhihua); Dong, LY (Dong, Lingyun); Su, X (Su, Xin); Zhang, BB (Zhang, Bingbing); Li, HY (Li, Hongyi)
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| 刊名 | CRYSTAL GROWTH & DESIGN
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| 出版日期 | 2013 |
| 卷号 | 13期号:8页码:3514-3521 |
| ISSN号 | 1528-7483 |
| 通讯作者 | Pan, SL |
| 中文摘要 | Two similarly stoichiometric borate halides, NaBa4(AlB4O9)2Br3 and NaBa4(B5O9)2F2Cl, have been successfully designed and synthesized, and their structures were determined by single-crystal X-ray diffraction. Their crystal structures feature the [AlB4O9]∞ and [B5O9]∞ networks, respectively. NaBa4(AlB4O9)2Br3 is noncentrosymmetric and crystallizes in polar space group P42nm, while NaBa4(B5O9)2F2Cl is centrosymmetric and crystallizes in monoclinic space group P21/n. Powder second-harmonic generation (SHG) measurements reveal that NaBa4(AlB4O9)2Br3 has an optical nonlinearity comparable to that of KH2PO4 (KDP) and is type I phase-matchable. In addition, infrared and UV–Vis–NIR diffuse reflectance spectroscopy, as well as electronic band structure calculations, were performed on the reported materials. |
| 收录类别 | SCI |
| 资助信息 | National Key Basic Research Program of China ；National Natural Science Foundation of China ；Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences |
| 公开日期 | 2013-11-05 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/2555]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, HW ,Pan, SL ,Wu, HP ,et al. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3[J]. CRYSTAL GROWTH & DESIGN,2013,13(8):3514-3521. |
| APA | Yu, HW .,Pan, SL .,Wu, HP .,Yang, ZH .,Dong, LY .,...&Li, HY .(2013).Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3.CRYSTAL GROWTH & DESIGN,13(8),3514-3521. |
| MLA | Yu, HW ,et al."Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3".CRYSTAL GROWTH & DESIGN 13.8(2013):3514-3521. |
入库方式： OAI收割
来源：新疆理化技术研究所
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