Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9
文献类型：期刊论文
| 作者 | Zhou Lin; Pan Shilie ; Su Xin; Yang Zhihua; Wu Hongping; Yu Hongwei; Zhang Fangfang; Cui Sifang; Zhou Zhongxiang
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| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2013 |
| 卷号 | 1049期号:10页码:473-478 |
| 关键词 | KPbB5O9 Synthesis Crystal structure Theoretical calculations |
| ISSN号 | 0022-2860 |
| 通讯作者 | Pan, SL |
| 中文摘要 | A new potassium lead pentaborate compound, KPbB5O9 has been synthesized by standard solid-state reaction for the first time. Its structure has been determined by single-crystal X-ray diffraction method. It crystallizes in the monoclinic space group P2(1)/c with lattice constants a = 6.717(3) angstrom, b = 8.389(3) angstrom, c = 13.686(5) angstrom, beta = 94.679(4)degrees and Z = 4. The structure consists of double ring B5O9 units, KO8 and PbO6 polyhedra. The PbO6 polyhedra linked together via corner-sharing O atom forming novel infinite (infinity)PbO6 chains along the b axis. Thermal analyses, IR spectroscopy and UV-vis-NIR diffuse reflectance spectrum, and band structure calculation were performed. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 资助信息 | 973 Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of CAS KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of CAS; Funds for Creative Cross & Cooperation Teams of CAS, Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period 201130111; High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Science and Technology Project of Urumqi G121130002 |
| 公开日期 | 2013-11-07 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/2631]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100039, Peoples R China;Huazhong Univ Sci & Technol, Sch Opt & Elect Informat, Wuhan 430074, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou Lin,Pan Shilie,Su Xin,et al. Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9[J]. JOURNAL OF MOLECULAR STRUCTURE,2013,1049(10):473-478. |
| APA | Zhou Lin.,Pan Shilie.,Su Xin.,Yang Zhihua.,Wu Hongping.,...&Zhou Zhongxiang.(2013).Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9.JOURNAL OF MOLECULAR STRUCTURE,1049(10),473-478. |
| MLA | Zhou Lin,et al."Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9".JOURNAL OF MOLECULAR STRUCTURE 1049.10(2013):473-478. |
入库方式： OAI收割
来源：新疆理化技术研究所
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