中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Introduction of isotopically heavy barium from back-arc basin hydrothermal systems into the ocean

文献类型:期刊论文

作者Zhang, Xia3; Sun, Zhilei1; Li, Tao2; Wu, Nengyou1,3; Cao, Hong1; Niu, Yaoling3
刊名CHEMICAL GEOLOGY
出版日期2025-11-05
卷号695页码:10
关键词Hydrothermal systems Ba isotopes Barite Okinawa Trough
ISSN号0009-2541
DOI10.1016/j.chemgeo.2025.123079
英文摘要

The concentrations of Ba in high-temperature hydrothermal fluids are several orders of magnitude higher than those in seawater and therefore may play an important role in marine Ba cycle. However, the ultimate hydrothermal inputs of Ba (isotopically light or heavy) into the oceans remain debated, and the Ba inputs from backarc hydrothermal vents are poorly constrained. To address this issue, we have analyzed the Ba isotope compositions of hydrothermal barites from the Okinawa Tough. The S138Ba values of the studied barites show a limited variation (S138Ba = -0.16 to -0.05 %o) compared to the natural range and is primarily controlled by the Rayleigh Ba isotope fractionation from the parental hydrothermal fluids during precipitation. About 33 to 51 % removal of Ba from the hydrothermal fluid will account for the observed S138Ba values. The S138Ba values of hydrothermal fluids after barite precipitation would be 0.19 to 0.30 %o, which are isotopically heavier than the Ba sinks in the ocean. The new data thus suggest that back-arc hydrothermal systems may introduce isotopically heavy Ba into the oceans due to the non-conservative behavior of Ba during the fluid-seawater mixing in these systems. The marine Ba budget has been evaluated and the calculated Ba inputs to the ocean are isotopically heavier than sediment outputs, implying either isotopically light sources or isotopically heavy sinks of Ba are missing. One possibility is that the light Ba released from MORB during low-temperature alteration may play an important role in maintaining marine Ba isotope budget balance.

WOS关键词OKINAWA TROUGH ; VENT FLUIDS ; ISOTOPE FRACTIONATION ; PHASE-SEPARATION ; STABLE-ISOTOPES ; RIDGE ; SEDIMENT ; GEOCHEMISTRY ; FIELD ; SULFUR
资助项目Natural Science Foundation of Shandong Province[ZR2024QD049] ; Natural Science Foundation of China (NSFC)[92358301] ; Natural Science Foundation of China (NSFC)[42176057] ; Foundation of Ministry of Natural Re-sources[DD20230402]
WOS研究方向Geochemistry & Geophysics
语种英语
WOS记录号WOS:001589294800001
出版者ELSEVIER
资助机构Natural Science Foundation of Shandong Province ; Natural Science Foundation of China (NSFC) ; Foundation of Ministry of Natural Re-sources
源URL[http://ir.nigpas.ac.cn/handle/332004/45757]  
专题中国科学院南京地质古生物研究所
通讯作者Sun, Zhilei
作者单位1.Minist Nat Resources, Qingdao Inst Marine Geol, Qingdao 266237, Peoples R China
2.Chinese Acad Sci, Nanjing Inst Geol & Palaeontol, Nanjing 210008, Peoples R China
3.Laoshan Lab, Qingdao 266237, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Xia,Sun, Zhilei,Li, Tao,et al. Introduction of isotopically heavy barium from back-arc basin hydrothermal systems into the ocean[J]. CHEMICAL GEOLOGY,2025,695:10.
APA Zhang, Xia,Sun, Zhilei,Li, Tao,Wu, Nengyou,Cao, Hong,&Niu, Yaoling.(2025).Introduction of isotopically heavy barium from back-arc basin hydrothermal systems into the ocean.CHEMICAL GEOLOGY,695,10.
MLA Zhang, Xia,et al."Introduction of isotopically heavy barium from back-arc basin hydrothermal systems into the ocean".CHEMICAL GEOLOGY 695(2025):10.

入库方式: OAI收割

来源:南京地质古生物研究所

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