Synthesis, structure, and properties of a novel hydrated borate Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O
文献类型：期刊论文
| 作者 | Zhao Yi; Pan Shilie ; Li Feng; Wang Yongjiang; Fan Xiaoyun; Dong Xiaoyu; Jia Dianzeng; Guo Jixi; Zhou Zhongxiang
|
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:1页码:82-87 |
| 关键词 | Rb-4B4O5(OH)(4)(2)center dot 3H(2)O Borate Crystal structure Crystal growth |
| ISSN号 | 1293-2558 |
| 通讯作者 | Pan, SL |
| 中文摘要 | Rb-4B4O5(OH)(4)2 center dot 3H(2)O has been grown by slow evaporation method with crystal sizes up to 11 mm x 7 mm x 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD). IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) angstrom, b = 7.7850(7) angstrom, c = 16.0763(16) angstrom, and Z = 4. It contains isolated B4O5(OH)(4)(2-) polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated B4O5(OH)(4)(2-) polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network. |
| 学科主题 | Chemistry ; Physics |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China 50802110; Chinese Academe of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; Xinjiang Uygur Autonomous Region of China 200816120 |
| 公开日期 | 2013-11-07 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/2811]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao Yi,Pan Shilie,Li Feng,et al. Synthesis, structure, and properties of a novel hydrated borate Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O[J]. SOLID STATE SCIENCES,2011,13(1):82-87. |
| APA | Zhao Yi.,Pan Shilie.,Li Feng.,Wang Yongjiang.,Fan Xiaoyun.,...&Zhou Zhongxiang.(2011).Synthesis, structure, and properties of a novel hydrated borate Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O.SOLID STATE SCIENCES,13(1),82-87. |
| MLA | Zhao Yi,et al."Synthesis, structure, and properties of a novel hydrated borate Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O".SOLID STATE SCIENCES 13.1(2011):82-87. |
入库方式： OAI收割
来源：新疆理化技术研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。