Hollow and Cage-Bell Structured Nanomaterials of Noble Metals
文献类型：期刊论文
| 作者 | Liu, Hui2; Qu, Jianglan2; Chen, Yunfa2 ; Li, Jianqiang2; Ye, Feng2; Lee, Jim Yang1; Yang, Jun2,3
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| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2012-07-18 |
| 卷号 | 134期号:28页码:11602-11610 |
| 关键词 | SILVER NANOPARTICLES MESOPOROUS SPHERES OXYGEN REDUCTION FACILE SYNTHESIS TITANIA SPHERES LITHIUM STORAGE PLATINUM HOLLOW DRUG-DELIVERY CAVITY SIZE NANOSPHERES |
| ISSN号 | 0002-7863 |
| 通讯作者 | Lee, JY |
| 英文摘要 | Mastery of the structure of nanomaterials enables control of their properties to enhance their performance for a given application. Herein we demonstrate the synthesis of metal nanomaterials with hollow interiors or cage-bell structures based on the inside-out diffusion of Ag in core-shell structured nanoparticles. It begins with the synthesis of core-shell Ag-M or core-shell-shell M-A-Ag-M-B nanoparticles in an organic solvent. Ag is then extracted from the core or the inner shell by bis(p-sulfonatophenyl)phenylphosphane, which binds strongly with Ag(I)/Ag(0) to allow the complete removal of Ag in 24-48 h, leaving behind an organosol of hollow or cage-bell structured metal nanomaterials. Because of their relatively lower densities, which usually translate to a higher surface area than their solid counterparts, the hollow and cage-bell structured metal nanomaterials are especially relevant to catalysis. For example, cage-bell structured Pt-Ru nanoparticles were found to display outstanding methanol tolerance for the cathode reaction of direct methanol fuel cells (DMFCs) as a result of the differential diffusion of methanol and oxygen in the cage-bell structure. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | SILVER NANOPARTICLES ; MESOPOROUS SPHERES ; OXYGEN REDUCTION ; FACILE SYNTHESIS ; TITANIA SPHERES ; LITHIUM STORAGE ; PLATINUM HOLLOW ; DRUG-DELIVERY ; CAVITY SIZE ; NANOSPHERES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000306457900049 |
| 公开日期 | 2013-10-16 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3553]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.Inst Bioengn & Nanotechnol, The Nanos 138669, Singapore |
| 推荐引用方式 GB/T 7714 | Liu, Hui,Qu, Jianglan,Chen, Yunfa,et al. Hollow and Cage-Bell Structured Nanomaterials of Noble Metals[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2012,134(28):11602-11610. |
| APA | Liu, Hui.,Qu, Jianglan.,Chen, Yunfa.,Li, Jianqiang.,Ye, Feng.,...&Yang, Jun.(2012).Hollow and Cage-Bell Structured Nanomaterials of Noble Metals.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,134(28),11602-11610. |
| MLA | Liu, Hui,et al."Hollow and Cage-Bell Structured Nanomaterials of Noble Metals".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 134.28(2012):11602-11610. |
入库方式： OAI收割
来源：过程工程研究所
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