中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2

文献类型:期刊论文

作者Chen, Xi1,2; Sun, Jian1; Wang, Jinquan1; Cheng, Weiguo1
刊名TETRAHEDRON LETTERS
出版日期2012-05-30
卷号53期号:22页码:2684-2688
关键词Cyclic carbonate Ionic liquids Polystyrene resin Diethanolamine
ISSN号0040-4039
通讯作者Cheng, WG
英文摘要Polystyrene-bound diethanolamine based ionic liquids (PS-DHEEAB and PS-THEAB) were synthesized and applied for the chemical fixation of CO2 into cyclic carbonates without any additional co-catalyst and solvent. The effect of the catalysts with different number of hydroxyl group in the cation of the IL on the reaction was systematically investigated. Highest activity and selectivity were achieved in the presence of polystyrene supported diethanolamine ethyl bromide (PS-DHEEAB) in comparison with other catalysts employed. The catalyst was tough in stability and also found to be extended to a variety of terminal epoxides and aziridines. The relationship between high catalytic reactivity and the -OH functional groups was proposed. (C) 2012 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CYCLIC CARBONATE SYNTHESIS ; CYCLOADDITION REACTIONS ; EFFICIENT CATALYSTS ; SALEN COMPLEXES ; DIOXIDE ; EPOXIDES ; IMMOBILIZATION ; ACTIVATION ; SILICA ; HALIDE
收录类别SCI
语种英语
WOS记录号WOS:000303953200003
公开日期2013-10-18
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/3811]  
专题过程工程研究所_多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, PR, Peoples R China
推荐引用方式
GB/T 7714
Chen, Xi,Sun, Jian,Wang, Jinquan,et al. Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2[J]. TETRAHEDRON LETTERS,2012,53(22):2684-2688.
APA Chen, Xi,Sun, Jian,Wang, Jinquan,&Cheng, Weiguo.(2012).Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2.TETRAHEDRON LETTERS,53(22),2684-2688.
MLA Chen, Xi,et al."Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2".TETRAHEDRON LETTERS 53.22(2012):2684-2688.

入库方式: OAI收割

来源:过程工程研究所

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