Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2
文献类型:期刊论文
作者 | Chen, Xi1,2; Sun, Jian1; Wang, Jinquan1; Cheng, Weiguo1 |
刊名 | TETRAHEDRON LETTERS
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出版日期 | 2012-05-30 |
卷号 | 53期号:22页码:2684-2688 |
关键词 | Cyclic carbonate Ionic liquids Polystyrene resin Diethanolamine |
ISSN号 | 0040-4039 |
通讯作者 | Cheng, WG |
英文摘要 | Polystyrene-bound diethanolamine based ionic liquids (PS-DHEEAB and PS-THEAB) were synthesized and applied for the chemical fixation of CO2 into cyclic carbonates without any additional co-catalyst and solvent. The effect of the catalysts with different number of hydroxyl group in the cation of the IL on the reaction was systematically investigated. Highest activity and selectivity were achieved in the presence of polystyrene supported diethanolamine ethyl bromide (PS-DHEEAB) in comparison with other catalysts employed. The catalyst was tough in stability and also found to be extended to a variety of terminal epoxides and aziridines. The relationship between high catalytic reactivity and the -OH functional groups was proposed. (C) 2012 Elsevier Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Organic |
研究领域[WOS] | Chemistry |
关键词[WOS] | CYCLIC CARBONATE SYNTHESIS ; CYCLOADDITION REACTIONS ; EFFICIENT CATALYSTS ; SALEN COMPLEXES ; DIOXIDE ; EPOXIDES ; IMMOBILIZATION ; ACTIVATION ; SILICA ; HALIDE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000303953200003 |
公开日期 | 2013-10-18 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/3811] ![]() |
专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, PR, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Xi,Sun, Jian,Wang, Jinquan,et al. Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2[J]. TETRAHEDRON LETTERS,2012,53(22):2684-2688. |
APA | Chen, Xi,Sun, Jian,Wang, Jinquan,&Cheng, Weiguo.(2012).Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2.TETRAHEDRON LETTERS,53(22),2684-2688. |
MLA | Chen, Xi,et al."Polystyrene-bound diethanolamine based ionic liquids for chemical fixation of CO2".TETRAHEDRON LETTERS 53.22(2012):2684-2688. |
入库方式: OAI收割
来源:过程工程研究所
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