Crystalline evolution of various CeO2 morphology via a solvothermal method
文献类型:期刊论文
作者 | Fu, Cong1; Li, Ruixing1; Tang, Qing2; Li, Chengqiang1; Yin, Shu3; Sato, Tsugio3 |
刊名 | RESEARCH ON CHEMICAL INTERMEDIATES
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出版日期 | 2011-04-01 |
卷号 | 37期号:2-5页码:319-327 |
关键词 | CeO2 Nanosize Morphology Solvothermal Synthesis |
ISSN号 | 0922-6168 |
通讯作者 | Li, RX |
英文摘要 | Preparation of cerium compounds with different structures and morphology is still a challenge in powder synthesis. CeOHCO3 and CeO2 have received widespread attention because of their potential applications. In this study, a solvothermal method with one-step precipitation was used to synthesize CeO2 with different structures and morphology without use of surfactant. The effects of different experimental conditions on the morphology of CeO2 were investigated. Both X-ray diffraction and SAED patterns revealed that products changed from a single CeOHCO3 phase to a mixture of CeOHCO3 and CeO2. A single Ce(O)2 phase could always be obtained from CeOHCO3 by calcination in air at 673 K for 1 h. Moreover, the morphology of CeOHCO3 was retained. Thus CeO2 particles with different morphology, for example rod-like, prism-like, polygon-like, sphere-like, and cube-like, could be synthesized. Possible mechanisms of phase and morphology evolution are discussed. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | THERMAL-CONVERSION ; SYSTEM ; MICROSTRUCTURES ; CEOHCO3 ; CE3+ |
收录类别 | SCI ; ISTP |
语种 | 英语 |
WOS记录号 | WOS:000291159400022 |
公开日期 | 2013-11-05 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/4873] ![]() |
专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
作者单位 | 1.Beihang Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Aerosp Mat & Performance, Beijing 100191, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 3.Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan |
推荐引用方式 GB/T 7714 | Fu, Cong,Li, Ruixing,Tang, Qing,et al. Crystalline evolution of various CeO2 morphology via a solvothermal method[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2011,37(2-5):319-327. |
APA | Fu, Cong,Li, Ruixing,Tang, Qing,Li, Chengqiang,Yin, Shu,&Sato, Tsugio.(2011).Crystalline evolution of various CeO2 morphology via a solvothermal method.RESEARCH ON CHEMICAL INTERMEDIATES,37(2-5),319-327. |
MLA | Fu, Cong,et al."Crystalline evolution of various CeO2 morphology via a solvothermal method".RESEARCH ON CHEMICAL INTERMEDIATES 37.2-5(2011):319-327. |
入库方式: OAI收割
来源:过程工程研究所
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