中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystalline evolution of various CeO2 morphology via a solvothermal method

文献类型:期刊论文

作者Fu, Cong1; Li, Ruixing1; Tang, Qing2; Li, Chengqiang1; Yin, Shu3; Sato, Tsugio3
刊名RESEARCH ON CHEMICAL INTERMEDIATES
出版日期2011-04-01
卷号37期号:2-5页码:319-327
关键词CeO2 Nanosize Morphology Solvothermal Synthesis
ISSN号0922-6168
通讯作者Li, RX
英文摘要Preparation of cerium compounds with different structures and morphology is still a challenge in powder synthesis. CeOHCO3 and CeO2 have received widespread attention because of their potential applications. In this study, a solvothermal method with one-step precipitation was used to synthesize CeO2 with different structures and morphology without use of surfactant. The effects of different experimental conditions on the morphology of CeO2 were investigated. Both X-ray diffraction and SAED patterns revealed that products changed from a single CeOHCO3 phase to a mixture of CeOHCO3 and CeO2. A single Ce(O)2 phase could always be obtained from CeOHCO3 by calcination in air at 673 K for 1 h. Moreover, the morphology of CeOHCO3 was retained. Thus CeO2 particles with different morphology, for example rod-like, prism-like, polygon-like, sphere-like, and cube-like, could be synthesized. Possible mechanisms of phase and morphology evolution are discussed.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]THERMAL-CONVERSION ; SYSTEM ; MICROSTRUCTURES ; CEOHCO3 ; CE3+
收录类别SCI ; ISTP
语种英语
WOS记录号WOS:000291159400022
公开日期2013-11-05
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/4873]  
专题过程工程研究所_多相复杂系统国家重点实验室
作者单位1.Beihang Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Aerosp Mat & Performance, Beijing 100191, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
3.Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
推荐引用方式
GB/T 7714
Fu, Cong,Li, Ruixing,Tang, Qing,et al. Crystalline evolution of various CeO2 morphology via a solvothermal method[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2011,37(2-5):319-327.
APA Fu, Cong,Li, Ruixing,Tang, Qing,Li, Chengqiang,Yin, Shu,&Sato, Tsugio.(2011).Crystalline evolution of various CeO2 morphology via a solvothermal method.RESEARCH ON CHEMICAL INTERMEDIATES,37(2-5),319-327.
MLA Fu, Cong,et al."Crystalline evolution of various CeO2 morphology via a solvothermal method".RESEARCH ON CHEMICAL INTERMEDIATES 37.2-5(2011):319-327.

入库方式: OAI收割

来源:过程工程研究所

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