Biomass pyrolysis in a micro-fluidized bed reactor: Characterization and kinetics
文献类型：期刊论文
| 作者 | Yu, Jian; Yao, Changbin; Zeng, Xi; Geng, Shuang; Dong, Li; Wang, Yin; Gao, Shiqiu; Xu, Guangwen |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2011-04-01 |
| 卷号 | 168期号:2页码:839-847 |
| 关键词 | Micro-fluidized bed Reaction kinetics Gas-solid reaction analysis Biomass Pyrolysis |
| ISSN号 | 1385-8947 |
| 通讯作者 | Gao, SQ |
| 英文摘要 | A micro-fluidized bed reactor (MFBR) was developed to enable (1) on-line pulse feeding and rapid heating of particle reactant, (2) effective suppression of the interfacial diffusion via fluidization, (3) minimization of intra-particle diffusion through adoption of fine solid reactants, and (4) on-line monitoring the composition of effluent product gas using, for example, process mass spectrometer. Application of the MFBR to biomass pyrolysis demonstrated that the reactor led the pyrolysis to have higher gas yield and less remaining carbon than the test in TG, and at 1173K the reaction finished in 10s. The time span to release an individual gas component appeared longest for H(2), shortest for CO(2) and equivalent for CH(4) and CO in between. Reaction kinetics was investigated with respect to the formation of individual gas component and pyrolysis gas mixture. The resulting activation energy and preexponential factor with respect to gas mixture were 11.77 kJ/mol and 1.45 s(-1), respectively. These values were obviously lower than those measured with TG and fixed bed reactors, reflecting the quick reaction nature enabled by the MFBR. A consequent comparison revealed further the factors that affect the values of the kinetic parameters. (C) 2011 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Environmental ; Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | THERMOGRAVIMETRIC ANALYSIS ; HEATING RATE ; WOOD ; MODEL ; DEVOLATILIZATION ; GASIFICATION ; TEMPERATURE ; COMPONENTS ; MECHANISM ; TG |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000290133700042 |
| 公开日期 | 2013-11-06 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5042]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Jian,Yao, Changbin,Zeng, Xi,et al. Biomass pyrolysis in a micro-fluidized bed reactor: Characterization and kinetics[J]. CHEMICAL ENGINEERING JOURNAL,2011,168(2):839-847. |
| APA | Yu, Jian.,Yao, Changbin.,Zeng, Xi.,Geng, Shuang.,Dong, Li.,...&Xu, Guangwen.(2011).Biomass pyrolysis in a micro-fluidized bed reactor: Characterization and kinetics.CHEMICAL ENGINEERING JOURNAL,168(2),839-847. |
| MLA | Yu, Jian,et al."Biomass pyrolysis in a micro-fluidized bed reactor: Characterization and kinetics".CHEMICAL ENGINEERING JOURNAL 168.2(2011):839-847. |
入库方式： OAI收割
来源：过程工程研究所
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