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Nitrogen-containing microporous carbon nanospheres with improved capacitive properties
文献类型：期刊论文
| 作者 | Su, Fabing1; Poh, Chee Kok2; Chen, Jun Song3; Xu, Guangwen1; Wang, Dan1; Li, Qin4; Lin, Jianyi2; Lou, Xiong Wen3 |
| 刊名 | ENERGY & ENVIRONMENTAL SCIENCE
 |
| 出版日期 | 2011-03-01 |
| 卷号 | 4期号:3页码:717-724 |
| 关键词 | DOUBLE-LAYER CAPACITANCE ELECTROCHEMICAL PERFORMANCE ELECTRODE MATERIAL DOPED POLYPYRROLE MATERIALS SCIENCE FUNCTIONAL-GROUPS ACTIVATED CARBON ENRICHED CARBONS SUPERCAPACITORS POLYANILINE |
| ISSN号 | 1754-5692 |
| 通讯作者 | Su, FB |
| 英文摘要 | We report the largely improved electrochemical capacitance of polypyrrole-derived microporous carbon nanospheres (MCNs, 80-100 nm in diameter) containing nitrogen functional groups. We have investigated the electrochemical properties of precursor polypyrrole nanospheres (PNs, with a high N/C ratio and low surface area) and as-derived carbon nanospheres (CNs, with a moderate N/C ratio and low surface area) prepared by carbonizing PNs at different temperatures, and MCNs (with a low N/C ratio and high surface area) obtained by chemical activation of CNs. The samples are thoroughly characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectroscopy, thermogravimetric analysis (TGA), nitrogen sorption, elemental analysis, and X-ray photoelectron spectroscopy (XPS). It is found that MCNs with a high surface area and N-doping species exhibit much better capacitive performance compared to the PNs and CNs, and commercial carbon blacks (XC-72 and BP2000) as well. The MCN sample gives a reversible specific capacitance of similar to 240 F g(-1) for 3000 cycles in aqueous media as a result of combined advantages of high electrochemical activity of doped heteroatoms (N and O) and accessible well-developed porosity, demonstrating the promising use in high-energy-density supercapacitors. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology ; Life Sciences & Biomedicine |
| 类目[WOS] | Chemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology |
| 关键词[WOS] | DOUBLE-LAYER CAPACITANCE ; ELECTROCHEMICAL PERFORMANCE ; ELECTRODE MATERIAL ; DOPED POLYPYRROLE ; MATERIALS SCIENCE ; FUNCTIONAL-GROUPS ; ACTIVATED CARBON ; ENRICHED CARBONS ; SUPERCAPACITORS ; POLYANILINE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287924700011 |
| 公开日期 | 2013-11-07 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5082]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Inst Chem Engn & Sci, Singapore 627833, Singapore 3.Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore 4.Curtin Univ Technol, Dept Chem Engn, Perth, WA 6845, Australia |
| 推荐引用方式 GB/T 7714 | Su, Fabing,Poh, Chee Kok,Chen, Jun Song,et al. Nitrogen-containing microporous carbon nanospheres with improved capacitive properties[J]. ENERGY & ENVIRONMENTAL SCIENCE,2011,4(3):717-724. |
| APA | Su, Fabing.,Poh, Chee Kok.,Chen, Jun Song.,Xu, Guangwen.,Wang, Dan.,...&Lou, Xiong Wen.(2011).Nitrogen-containing microporous carbon nanospheres with improved capacitive properties.ENERGY & ENVIRONMENTAL SCIENCE,4(3),717-724. |
| MLA | Su, Fabing,et al."Nitrogen-containing microporous carbon nanospheres with improved capacitive properties".ENERGY & ENVIRONMENTAL SCIENCE 4.3(2011):717-724. |
入库方式： OAI收割
来源：过程工程研究所
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