Aerobic Oxidation of Benzyl Alcohol over Activated Carbon Supported Manganese and Vanadium Catalysts: Effect of Surface Oxygen-Containing Groups
文献类型：期刊论文
| 作者 | Chen, Yuanting1; Chen, Wan1; Tang, Qinghu1; Guo, Zhen1; Yang, Yanhui1; Su, Fabing2 |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2011 |
| 卷号 | 141期号:1页码:149-157 |
| 关键词 | Activated carbon Surface oxygen Manganese oxides Vanadium oxides Benzyl alcohol oxidation |
| ISSN号 | 1011-372X |
| 通讯作者 | Yang, YH |
| 英文摘要 | In this contribution, the selective oxidation of benzyl alcohol using molecular oxygen over supported manganese and vanadium catalysts was investigated. The catalytic activities were significantly improved after pre-oxidizing the activated carbon support materials. Characterizations of nitrogen physisorption, X-ray diffraction, transmission electron microscopy, and X-ray absorption were involved to examine the physicochemical properties of as-prepared catalysts. By ruling out the effects of specific surface area, active site dispersion, valence and local coordination of Mn and V active species, the improved catalytic activity was attributed to the specific variety and increased density of oxygen-containing groups on activated carbon support surfaces, which was further confirmed by cyclic voltammetry measurements and Fourier transform infrared spectroscopy. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ABSORPTION FINE-STRUCTURE ; SELECTIVE OXIDATION ; RUTHENIUM CATALYSTS ; AROMATIC ALCOHOLS ; PLATINUM ; CINNAMALDEHYDE ; HYDROGENATION ; CHEMISTRY ; PERFORMANCE ; EPOXIDATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000286380900019 |
| 公开日期 | 2013-11-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5258]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore 2.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Yuanting,Chen, Wan,Tang, Qinghu,et al. Aerobic Oxidation of Benzyl Alcohol over Activated Carbon Supported Manganese and Vanadium Catalysts: Effect of Surface Oxygen-Containing Groups[J]. CATALYSIS LETTERS,2011,141(1):149-157. |
| APA | Chen, Yuanting,Chen, Wan,Tang, Qinghu,Guo, Zhen,Yang, Yanhui,&Su, Fabing.(2011).Aerobic Oxidation of Benzyl Alcohol over Activated Carbon Supported Manganese and Vanadium Catalysts: Effect of Surface Oxygen-Containing Groups.CATALYSIS LETTERS,141(1),149-157. |
| MLA | Chen, Yuanting,et al."Aerobic Oxidation of Benzyl Alcohol over Activated Carbon Supported Manganese and Vanadium Catalysts: Effect of Surface Oxygen-Containing Groups".CATALYSIS LETTERS 141.1(2011):149-157. |
入库方式： OAI收割
来源：过程工程研究所
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