A thermodynamic model of calculating mass action concentrations for structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions and NaClO4-NaF-H2O ternary solution
文献类型：期刊论文
| 作者 | Yang, Xue-min1; Zhao, Wei-jie2,3; Guo, Han-jie2; Zhang, Qiang3; Zhang, Jian2 |
| 刊名 | INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
 |
| 出版日期 | 2010-10-01 |
| 卷号 | 17期号:5页码:546-557 |
| 关键词 | binary systems ternary systems thermodynamic model activity coefficient structural unit |
| ISSN号 | 1674-4799 |
| 通讯作者 | Yang, XM |
| 英文摘要 | A thermodynamic model of calculating mass action concentrations for structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions and NaClO4-NaF-H2O ternary strong electrolyte aqueous solutions was developed based on the ion and molecule coexistence theory (IMCT). A transformation coefficient was needed to compare the calculated mass action concentration and the reported activity, because they were usually obtained at different standard states and concentration units. The results show that transformation coefficients between the calculated mass action concentrations and the reported activities of the same components change in a very narrow range. The transformed mass action concentrations of structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions agree well with the reported activities. The transformed mass action concentrations of structural units or ion couples in NaClO4-NaF-H2O ternary solution are also in good agreement with the reported activities in a total ionic strength range from 0.1 to 0.9 mol/kg H2O by the 0.1 mol/kg step with different ionic strength fractions of 0, 0.2, 0.4, 0.5, 0.6, 0.8, and 1, respectively. The results indicate that the developed thermodynamic model can reveal the structural characteristics of binary and ternary strong electrolyte aqueous solutions, and the calculated mass action concentrations of structural units or ion couples also strictly follow the mass action law. |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| 类目[WOS] | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing |
| 研究领域[WOS] | Materials Science ; Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing |
| 关键词[WOS] | WATER ACTIVITIES ; SYSTEM ; MELTS ; MIXTURES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000282627800007 |
| 公开日期 | 2013-11-12 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5700]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Sci & Technol Beijing, Sch Met & Ecol Engn, Beijing 100083, Peoples R China 3.China Met Grp Corp, Beijing Met Equipment Res & Design Corp Ltd, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xue-min,Zhao, Wei-jie,Guo, Han-jie,et al. A thermodynamic model of calculating mass action concentrations for structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions and NaClO4-NaF-H2O ternary solution[J]. INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,2010,17(5):546-557. |
| APA | Yang, Xue-min,Zhao, Wei-jie,Guo, Han-jie,Zhang, Qiang,&Zhang, Jian.(2010).A thermodynamic model of calculating mass action concentrations for structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions and NaClO4-NaF-H2O ternary solution.INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,17(5),546-557. |
| MLA | Yang, Xue-min,et al."A thermodynamic model of calculating mass action concentrations for structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions and NaClO4-NaF-H2O ternary solution".INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS 17.5(2010):546-557. |
入库方式： OAI收割
来源：过程工程研究所
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