Analysis of the ionic conduction in Y2O3-stabilized ZrO2 at low temperatures by impedance spectroscopy
文献类型:会议论文
作者 | Chen, Y. F.![]() ![]() ![]() |
出版日期 | 2002 |
会议名称 | 2nd China International Conference on High-Performance Ceramics (CICC-2) |
会议日期 | NOV 11-15, 2001 |
会议地点 | KUNMING, PEOPLES R CHINA |
关键词 | ionic conductivity zirconia complex impedance yttria-stabilized zirconia ac conductivity single-crystals energies model |
页码 | 163-168 |
中文摘要 | The AC conductivity, sigma(ac) of an 8mol%-yttria-stabilized zirconia ceramic was obtained as a function of frequency, f, from complex impedance measurements in the temperature range between 313 and 473 K. By analyzing the conductivity spectra according to the universal dynamic response (UDR) expression, sigma(ac), = sigma(dc), [1 +(f/f(P))(5)], a set of parameters, including the DC conductivity sigma(dc),, the carrier hopping rate omega(H) and the effective carrier concentration n, were extracted to describe the ionic mobility and to yield the activation energies for different processes associated with ionic conduction. It was found that the activation energy for ionic conduction, E, increases with increasing temperature, being rather different with those observed in high temperature range. The effect of ionic mobility on the activation energy E was then discussed briefly and a possible explanation for the observed temperature dependence of E was proposed. |
收录类别 | CPCI |
会议网址 | |
会议录 | HIGH-PERFORMANCE CERAMICS 2001, PROCEEDINGS 丛书: KEY ENGINEERING MATERIALS
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会议录出版者 | Trans Tech Publications Ltd |
语种 | 英语 |
源URL | [http://ir.ipe.ac.cn/handle/122111/5619] ![]() |
专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
推荐引用方式 GB/T 7714 |
Chen, Y. F.,Chen, Y. F.,Chen, Y. F.. Analysis of the ionic conduction in Y2O3-stabilized ZrO2 at low temperatures by impedance spectroscopy[C]. 见:2nd China International Conference on High-Performance Ceramics (CICC-2). KUNMING, PEOPLES R CHINA. NOV 11-15, 2001. |
入库方式: OAI收割
来源:过程工程研究所
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