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Hydrogen Bonds: A Structural Insight into Ionic Liquids
文献类型：期刊论文
| 作者 | Dong, Kun; Zhang, Suojiang |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2012-03-01 |
| 卷号 | 18期号:10页码:2748-2761 |
| 关键词 | hydrogen bonds noncovalent interactions ionic liquids physical properties |
| ISSN号 | 0947-6539 |
| 通讯作者 | Zhang, SJ |
| 英文摘要 | Ionic liquids (ILs) have attracted intensive attention in academia and industry due to their unique properties and potential applications. Nowadays, much interest is focused on finding out what is the main force that determines the properties of ionic liquids. Intuitively like NaCl, in high-temperature molten salt (HTMS) the electrostatic Coulomb force is regarded as the dominant factor that determines the behaviors of ILs. However, a large amount of evidence indicates that such a molten-salt-based simplified explanation is not consistent with the corresponding experimental results. Besides the Coulomb force, the hydrogen bond is another important noncovalent interaction in the IL and is closely related to some important properties and applications, as suggested in some new research results. Therefore in this review, we present results concerning the hydrogen bond in ILs, from the perspective of experiment and calculation, to shed light on its effects and roles. The deep insights into structure, in particular the hydrogen bonds, can provide us with a rational design for the new ILs to fulfill the demands in some complicated chemical processes. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | DIELS-ALDER REACTIONS ; X-RAY-DIFFRACTION ; CARBON-DIOXIDE ; HIGH-PRESSURE ; AB-INITIO ; 1-N-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE ; 1,3-DIMETHYLIMIDAZOLIUM CHLORIDE ; NANOSTRUCTURAL ORGANIZATION ; PHYSICOCHEMICAL PROPERTIES ; THERMODYNAMIC PROPERTIES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000300837100001 |
| 公开日期 | 2013-10-22 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3863]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Kun,Zhang, Suojiang. Hydrogen Bonds: A Structural Insight into Ionic Liquids[J]. CHEMISTRY-A EUROPEAN JOURNAL,2012,18(10):2748-2761. |
| APA | Dong, Kun,&Zhang, Suojiang.(2012).Hydrogen Bonds: A Structural Insight into Ionic Liquids.CHEMISTRY-A EUROPEAN JOURNAL,18(10),2748-2761. |
| MLA | Dong, Kun,et al."Hydrogen Bonds: A Structural Insight into Ionic Liquids".CHEMISTRY-A EUROPEAN JOURNAL 18.10(2012):2748-2761. |
入库方式： OAI收割
来源：过程工程研究所
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