Densities and Viscosities of the Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with N-Methyl-2-pyrrolidone or Ethanol at T = (293.15 to 323.15) K
文献类型:期刊论文
作者 | Yao, Hongwei1,2; Zhang, Shuheng1,2; Wang, Jieli1,3; Zhou, Qing1; Dong, Haifeng1; Zhang, Xiangping1 |
刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
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出版日期 | 2012-03-01 |
卷号 | 57期号:3页码:875-881 |
关键词 | TEMPERATURE IONIC LIQUID CARBON-DIOXIDE SOLVENTS WATER 25-DEGREES-C CATALYSIS SYSTEMS |
ISSN号 | 0021-9568 |
通讯作者 | Zhang, XP |
英文摘要 | The densities and viscosities of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl))imide ([EMIM][NTf2]) + N-methyl-2-pyrrolidone (NMP) and [EMIM] [NTf2] + ethanol mixtures were investigated over the mole fraction range from (0.1 to 0.9) and at temperatures from (293.15 to 323.15) K at intervals of 5 K. The densities can be well-represented by the quadratic equation, and the viscosities can be represented in the form of the Vogel equation. The excess molar volumes (V-E) and viscosity deviations (Delta eta) were calculated, and the results were fitted to the Redlich-Kister equation using a multiparametric nonlinear regression method. The estimated parameters of the Redlich-Kister equation and standard deviation were also presented. The results showed that the densities and viscosities were dependent strongly on NMP or ethanol content. Comparatively, the viscosity deviation Delta eta was more sensitive to temperature than the excess molar volume V-E. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Multidisciplinary ; Engineering, Chemical |
研究领域[WOS] | Chemistry ; Engineering |
关键词[WOS] | TEMPERATURE IONIC LIQUID ; CARBON-DIOXIDE ; SOLVENTS ; WATER ; 25-DEGREES-C ; CATALYSIS ; SYSTEMS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000301169900028 |
公开日期 | 2013-10-23 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/3888] ![]() |
专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
作者单位 | 1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 3.Beijing Univ Chem Technol, Coll Chem Engn & Technol, Beijing 100029, Peoples R China |
推荐引用方式 GB/T 7714 | Yao, Hongwei,Zhang, Shuheng,Wang, Jieli,et al. Densities and Viscosities of the Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with N-Methyl-2-pyrrolidone or Ethanol at T = (293.15 to 323.15) K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2012,57(3):875-881. |
APA | Yao, Hongwei,Zhang, Shuheng,Wang, Jieli,Zhou, Qing,Dong, Haifeng,&Zhang, Xiangping.(2012).Densities and Viscosities of the Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with N-Methyl-2-pyrrolidone or Ethanol at T = (293.15 to 323.15) K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,57(3),875-881. |
MLA | Yao, Hongwei,et al."Densities and Viscosities of the Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with N-Methyl-2-pyrrolidone or Ethanol at T = (293.15 to 323.15) K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 57.3(2012):875-881. |
入库方式: OAI收割
来源:过程工程研究所
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