中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Densities and Viscosities of the Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with N-Methyl-2-pyrrolidone or Ethanol at T = (293.15 to 323.15) K

文献类型:期刊论文

作者Yao, Hongwei1,2; Zhang, Shuheng1,2; Wang, Jieli1,3; Zhou, Qing1; Dong, Haifeng1; Zhang, Xiangping1
刊名JOURNAL OF CHEMICAL AND ENGINEERING DATA
出版日期2012-03-01
卷号57期号:3页码:875-881
关键词TEMPERATURE IONIC LIQUID CARBON-DIOXIDE SOLVENTS WATER 25-DEGREES-C CATALYSIS SYSTEMS
ISSN号0021-9568
通讯作者Zhang, XP
英文摘要The densities and viscosities of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl))imide ([EMIM][NTf2]) + N-methyl-2-pyrrolidone (NMP) and [EMIM] [NTf2] + ethanol mixtures were investigated over the mole fraction range from (0.1 to 0.9) and at temperatures from (293.15 to 323.15) K at intervals of 5 K. The densities can be well-represented by the quadratic equation, and the viscosities can be represented in the form of the Vogel equation. The excess molar volumes (V-E) and viscosity deviations (Delta eta) were calculated, and the results were fitted to the Redlich-Kister equation using a multiparametric nonlinear regression method. The estimated parameters of the Redlich-Kister equation and standard deviation were also presented. The results showed that the densities and viscosities were dependent strongly on NMP or ethanol content. Comparatively, the viscosity deviation Delta eta was more sensitive to temperature than the excess molar volume V-E.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Multidisciplinary ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]TEMPERATURE IONIC LIQUID ; CARBON-DIOXIDE ; SOLVENTS ; WATER ; 25-DEGREES-C ; CATALYSIS ; SYSTEMS
收录类别SCI
语种英语
WOS记录号WOS:000301169900028
公开日期2013-10-23
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/3888]  
专题过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
3.Beijing Univ Chem Technol, Coll Chem Engn & Technol, Beijing 100029, Peoples R China
推荐引用方式
GB/T 7714
Yao, Hongwei,Zhang, Shuheng,Wang, Jieli,et al. Densities and Viscosities of the Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with N-Methyl-2-pyrrolidone or Ethanol at T = (293.15 to 323.15) K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2012,57(3):875-881.
APA Yao, Hongwei,Zhang, Shuheng,Wang, Jieli,Zhou, Qing,Dong, Haifeng,&Zhang, Xiangping.(2012).Densities and Viscosities of the Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with N-Methyl-2-pyrrolidone or Ethanol at T = (293.15 to 323.15) K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,57(3),875-881.
MLA Yao, Hongwei,et al."Densities and Viscosities of the Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with N-Methyl-2-pyrrolidone or Ethanol at T = (293.15 to 323.15) K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 57.3(2012):875-881.

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来源:过程工程研究所

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