Experimental Measurement and Modeling of Aniline Hydrochloride Solubility in Water, Methanol, Ethanol, Propan-1-ol, and Their Mixed Systems
文献类型：期刊论文
| 作者 | Sun, Shunping; Li, Zhibao |
| 刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
 |
| 出版日期 | 2012 |
| 卷号 | 57期号:1页码:219-226 |
| 关键词 | ELECTROLYTE NRTL MODEL EXCESS GIBBS ENERGY SOLID-LIQUID EQUILIBRIUM AQUEOUS-ORGANIC SYSTEMS LOCAL COMPOSITION MODEL VAPOR-LIQUID THERMODYNAMIC REPRESENTATION PHASE-EQUILIBRIA SALT SYSTEMS SOLVENT |
| ISSN号 | 0021-9568 |
| 通讯作者 | Li, ZB |
| 英文摘要 | The solubilities of aniline hydrochloride ([HAE]Cl) in different aqueous solutions of methanol, ethanol, propan-1-ol, and their mixed solvent solutions were determined using the dynamic method in the temperature range between 288 K and 328 K. With the purpose of improving AspenPlus's prediction capability, in regards to [HAE]Cl solubilities in the CH(3)OH-C(2)H(5)OH-C(3)H(7)OH-H(2)O system at various temperatures, new interaction energy parameters tau([HAE]+-Cl-),(CH3OH)tau(CH3OH),([HAE]+-Cl-), tau([HAE]+-Cl-),(C2H5OH)tau(C2H5OH),([HAE]+-Cl-), and tau([HAE]+-Cl-),(C3H7OH)tau(C3H7OH,[HAE]+-Cl-) were obtained via regression of the experimental solubility of [HAE]Cl in binary mixed solvent systems with the maximum-likelihood principle. With the newly obtained electrolyte nonrandom two-liquid (NRTL) interaction parameters, a self-consistent model was established for the calculation of [HAE]Cl solubility in the system of CH(3)OH-C(2)H(5)OH-C(3)H(7)OH-H(2)O as a function of temperature and the composition of solvents. The maximum relative deviation between experimental and predicted solubility data is 2.3%, and the average relative deviation is 1.8 %. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Multidisciplinary ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | ELECTROLYTE NRTL MODEL ; EXCESS GIBBS ENERGY ; SOLID-LIQUID EQUILIBRIUM ; AQUEOUS-ORGANIC SYSTEMS ; LOCAL COMPOSITION MODEL ; VAPOR-LIQUID ; THERMODYNAMIC REPRESENTATION ; PHASE-EQUILIBRIA ; SALT SYSTEMS ; SOLVENT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000298978900034 |
| 公开日期 | 2013-10-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4330]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Shunping,Li, Zhibao. Experimental Measurement and Modeling of Aniline Hydrochloride Solubility in Water, Methanol, Ethanol, Propan-1-ol, and Their Mixed Systems[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2012,57(1):219-226. |
| APA | Sun, Shunping,&Li, Zhibao.(2012).Experimental Measurement and Modeling of Aniline Hydrochloride Solubility in Water, Methanol, Ethanol, Propan-1-ol, and Their Mixed Systems.JOURNAL OF CHEMICAL AND ENGINEERING DATA,57(1),219-226. |
| MLA | Sun, Shunping,et al."Experimental Measurement and Modeling of Aniline Hydrochloride Solubility in Water, Methanol, Ethanol, Propan-1-ol, and Their Mixed Systems".JOURNAL OF CHEMICAL AND ENGINEERING DATA 57.1(2012):219-226. |
入库方式： OAI收割
来源：过程工程研究所
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