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Non-isothermal thermal decomposition reaction kinetics of dimethylhexane-1,6-dicarbamate (HDC)
文献类型：期刊论文
| 作者 | Li, Xintao; Li, Huiquan; Liu, Haitao; Zhu, Ganyu |
| 刊名 | JOURNAL OF HAZARDOUS MATERIALS
 |
| 出版日期 | 2011-12-30 |
| 卷号 | 198期号:0页码:376-380 |
| ISSN号 | 0304-3894 |
| 关键词 | Dimethylhexane-1 Non-isothermal kinetics TG-DTG DSC Thermal decomposition 6-dicarbamate (HDC) |
| 通讯作者 | Li, HQ |
| 英文摘要 | The thermal decomposition behavior and reaction kinetics of dimethylhexane-1,6-dicarbamate (HDC) were investigated by TG-DTG. DSC and IR techniques. It is shown that the decomposition process can be divided into 3 main stages and the first stage is the thermal decomposition reaction for HDC to dimethylhexane-1,6-diisocyanate (HDI). The main gaseous products of the decomposition are CO2 and CH3OH. The kinetic parameters of the reaction for HDC to HDI are Ea =119.51 kJ mol(-1), Ig(A/s(-1)) = 14.82, respectively. The kinetic equation is d(alpha)/d(t). 10(15.12)(1 - alpha)(3/2) e(-1.4375x104)/T. (C) 2011 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology ; Life Sciences & Biomedicine |
| 类目[WOS] | Engineering, Environmental ; Engineering, Civil ; Environmental Sciences |
| 研究领域[WOS] | Engineering ; Environmental Sciences & Ecology |
| 关键词[WOS] | DIMETHYL CARBONATE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000298778700047 |
| 公开日期 | 2013-10-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4334]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xintao,Li, Huiquan,Liu, Haitao,et al. Non-isothermal thermal decomposition reaction kinetics of dimethylhexane-1,6-dicarbamate (HDC)[J]. JOURNAL OF HAZARDOUS MATERIALS,2011,198(0):376-380. |
| APA | Li, Xintao,Li, Huiquan,Liu, Haitao,&Zhu, Ganyu.(2011).Non-isothermal thermal decomposition reaction kinetics of dimethylhexane-1,6-dicarbamate (HDC).JOURNAL OF HAZARDOUS MATERIALS,198(0),376-380. |
| MLA | Li, Xintao,et al."Non-isothermal thermal decomposition reaction kinetics of dimethylhexane-1,6-dicarbamate (HDC)".JOURNAL OF HAZARDOUS MATERIALS 198.0(2011):376-380. |
入库方式： OAI收割
来源：过程工程研究所
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