Intrinsic kinetics of oxidative dehydrogenation of propane in the presence of CO2 over Cr/MSU-1 catalyst
文献类型：期刊论文
| 作者 | Liu, Haitao; Zhang, Zhao; Li, Huiquan; Huang, Qingze |
| 刊名 | JOURNAL OF NATURAL GAS CHEMISTRY
 |
| 出版日期 | 2011-05-01 |
| 卷号 | 20期号:3页码:311-317 |
| 关键词 | intrinsic kinetics propane carbon dioxide oxidative dehydrogenation Cr/MSU-1 catalyst |
| ISSN号 | 1003-9953 |
| 通讯作者 | Li, HQ |
| 英文摘要 | The intrinsic kinetics of oxidative dehydrogenation of propane with CO2 has been investigated over Cr/MSU-1 catalyst in a fixed bed reactor. Without limitations of both internal and external diffusion, intrinsic kinetic data were obtained under the following conditions: 490-530 degrees C, space velocity of 3600-6000 mL.h(-1).g(-1) and 3/1 molar ratio for CO2/C3H8 under normal pressure. Based on Langmuir-Hinshelwood mechanism, the kinetic models were established, and they were validated by statistical analysis. The parameters were estimated using Simplex Method combined with Universal Global Optimization Algorithm. The model, taking the surface reaction process as the rate-determining step, is the best one in agreement with the experimental data. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering |
| 关键词[WOS] | OXIDE CATALYSTS ; MESOPOROUS SILICA ; CARBON-DIOXIDE ; VANADIUM ; OXIDEHYDROGENATION ; PERFORMANCE ; PROPYLENE ; PROPENE ; ETHANE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000291846100015 |
| 公开日期 | 2013-11-05 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4859]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | Chinese Acad Sci, Inst Proc & Engn, Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Haitao,Zhang, Zhao,Li, Huiquan,et al. Intrinsic kinetics of oxidative dehydrogenation of propane in the presence of CO2 over Cr/MSU-1 catalyst[J]. JOURNAL OF NATURAL GAS CHEMISTRY,2011,20(3):311-317. |
| APA | Liu, Haitao,Zhang, Zhao,Li, Huiquan,&Huang, Qingze.(2011).Intrinsic kinetics of oxidative dehydrogenation of propane in the presence of CO2 over Cr/MSU-1 catalyst.JOURNAL OF NATURAL GAS CHEMISTRY,20(3),311-317. |
| MLA | Liu, Haitao,et al."Intrinsic kinetics of oxidative dehydrogenation of propane in the presence of CO2 over Cr/MSU-1 catalyst".JOURNAL OF NATURAL GAS CHEMISTRY 20.3(2011):311-317. |
入库方式： OAI收割
来源：过程工程研究所
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