Kinetic Study of Methoxycarbonylation of Methylene Dianiline with Dimethyl Carbonate Using Lead Acetate Catalyst
文献类型：期刊论文
| 作者 | Pei, Yixia1,2; Li, Huiquan1; Liu, Haitao1; Zhang, Yi1 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2011-02-16 |
| 卷号 | 50期号:4页码:1955-1961 |
| 关键词 | ZINC ACETATE CARBONYLATION COHESIVE PARTICLES DIISOCYANATE CARBAMATE DIAMINE AMINES |
| ISSN号 | 0888-5885 |
| 通讯作者 | Li, HQ |
| 英文摘要 | Methylene diphenyl dicarbamate (MDC) is a. key intermediate in the non phosgene manufacture of methylene diphenyl diisocyanate. The synthesis of MDC by methoxycarbonylation of methylene dianiline (MDA) with dimethyl carbonate in the presence of lead acetate catalyst, which showed high catalytic activity, was studied. Complete conversion of MDA and 98.10% yield of MDC were achieved under optimum conditions. To quantify the influence of both the temperature and reaction time, the kinetic parameters were investigated in the presence of Pb(OAc)(2)center dot 3H(2)O. A consecutive reaction model was established by simplifying the methoxycarbonylation process, and the two steps were confirmed to be first-order reactions by the integral test method and the numerical differential method, respectively. The results showed that the activation energies of the two steps are 175.84 and 177.92 kJ/mol, with the frequency factors being 1.91 x 10(20) and 1.98 x 10(20), respectively. Based on the kinetic model obtained, the progress of the reaction can be calculated under given conditions. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | ZINC ACETATE ; CARBONYLATION ; DIISOCYANATE ; CARBAMATE ; DIAMINE ; AMINES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287049700020 |
| 公开日期 | 2013-11-07 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5088]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pei, Yixia,Li, Huiquan,Liu, Haitao,et al. Kinetic Study of Methoxycarbonylation of Methylene Dianiline with Dimethyl Carbonate Using Lead Acetate Catalyst[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2011,50(4):1955-1961. |
| APA | Pei, Yixia,Li, Huiquan,Liu, Haitao,&Zhang, Yi.(2011).Kinetic Study of Methoxycarbonylation of Methylene Dianiline with Dimethyl Carbonate Using Lead Acetate Catalyst.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,50(4),1955-1961. |
| MLA | Pei, Yixia,et al."Kinetic Study of Methoxycarbonylation of Methylene Dianiline with Dimethyl Carbonate Using Lead Acetate Catalyst".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 50.4(2011):1955-1961. |
入库方式： OAI收割
来源：过程工程研究所
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