Iron(III)-based ionic liquid-catalyzed regioselective benzylation of arenes and heteroarenes
文献类型：期刊论文
| 作者 | Gao, Jian1,2; Wang, Jin-Quan3; Song, Qing-Wen1,2; He, Liang-Nian1,2 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:5页码:1182-1186 |
| 关键词 | EFFICIENT ALKYLATION ALCOHOLS DODECENE STYRENES |
| ISSN号 | 1463-9262 |
| 通讯作者 | Gao, J |
| 英文摘要 | An easily prepared Fe(III)-derived Lewis acid ionic liquid ([C(4)mim][FeCl(4)]), being comprised of 1-butyl-3-methyl imidazolium cation and tetrachloroferrate anion, was found to be an efficient, recyclable catalyst for benzylation of various arenes/heteroarenes into the diarylmethanes derivatives under mild reaction conditions without utilization of additional organic solvent. Interestingly, the acidity of [C(4)mim][FeCl(4)] could account for its catalytic activity in promoting the Lewis acid-catalyzed alkylation. Notably, this type of Fe(III)-based ionic liquid (IL) shows excellent stability, and could be easily recovered, and reused for five times without significant loss of its catalytic activity. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | EFFICIENT ; ALKYLATION ; ALCOHOLS ; DODECENE ; STYRENES |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000290227800022 |
| 公开日期 | 2013-11-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5389]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China 2.Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Jian,Wang, Jin-Quan,Song, Qing-Wen,et al. Iron(III)-based ionic liquid-catalyzed regioselective benzylation of arenes and heteroarenes[J]. GREEN CHEMISTRY,2011,13(5):1182-1186. |
| APA | Gao, Jian,Wang, Jin-Quan,Song, Qing-Wen,&He, Liang-Nian.(2011).Iron(III)-based ionic liquid-catalyzed regioselective benzylation of arenes and heteroarenes.GREEN CHEMISTRY,13(5),1182-1186. |
| MLA | Gao, Jian,et al."Iron(III)-based ionic liquid-catalyzed regioselective benzylation of arenes and heteroarenes".GREEN CHEMISTRY 13.5(2011):1182-1186. |
入库方式： OAI收割
来源：过程工程研究所
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