Selective Liquefaction of Wheat Straw in Phenol and Its Fractionation
文献类型：期刊论文
| 作者 | Chen, Hongzhang ; Zhang, Yuzhen; Xie, Shuangping
|
| 刊名 | APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY
 |
| 出版日期 | 2012-05-01 |
| 卷号 | 167期号:2页码:250-258 |
| 关键词 | Selective liquefaction Fractionation Biomass Resin adhesive Enzymatic hydrolysis |
| ISSN号 | 0273-2289 |
| 通讯作者 | Chen, HZ |
| 英文摘要 | For the first time, a method of phenol-selective liquefaction is proposed for the fractionation and multilevel conversion of lignocellulose. Through phenol-selective liquefaction, lignin and hemicellulose are liquefied, with large amounts of cellulose retained in the unliquefied residues. Using a phenol/straw ratio of 3 and a sulfuric acid concentration of 3 %, large amounts of hemicellulose (a parts per thousand yen85 %) and lignin (a parts per thousand yen70 %) can be liquefied at 100 A degrees C in 30 min, with a high quantity of cellulose (a parts per thousand yen80 %) retained. Unliquefied residues from selective liquefaction have higher susceptibility for enzymatic attack. Enzymatic hydrolyzation of residues can be as high as 65 % in 48 h with 40.7 FPU/g of dry materials, which can then be used to prepare sugar platform intermediates. The liquefied products of wheat straw are then resinified with formaldehyde in the presence of NaOH as a catalyst and synthesized into phenol formaldehyde-type resins reaching up to GB/T 14732-2006 standards. Phenol selective liquefaction, a new technology for the fractionation of lignocellulose, achieves effective fractionation and multilevel conversion of straw components. Hence, it is an important tool to achieve full utilization of biomass and high value-added conversion of lignocellulose. |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine |
| 类目[WOS] | Biochemistry & Molecular Biology ; Biotechnology & Applied Microbiology |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Biotechnology & Applied Microbiology |
| 关键词[WOS] | ENZYMATIC-HYDROLYSIS ; PRETREATMENT ; GLYCEROL ; ADHESIVE ; BIOMASS ; PRODUCT ; WASTE ; RESIN ; WOOD |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000304204300005 |
| 公开日期 | 2013-10-18 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3812]  |
| 专题 | 过程工程研究所_生化工程国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Hongzhang,Zhang, Yuzhen,Xie, Shuangping. Selective Liquefaction of Wheat Straw in Phenol and Its Fractionation[J]. APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY,2012,167(2):250-258. |
| APA | Chen, Hongzhang,Zhang, Yuzhen,&Xie, Shuangping.(2012).Selective Liquefaction of Wheat Straw in Phenol and Its Fractionation.APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY,167(2),250-258. |
| MLA | Chen, Hongzhang,et al."Selective Liquefaction of Wheat Straw in Phenol and Its Fractionation".APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY 167.2(2012):250-258. |
入库方式： OAI收割
来源：过程工程研究所
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