One-Step Separation of Platinum, Palladium, and Rhodium: A Three-Liquid-Phase Extraction Approach
文献类型：期刊论文
| 作者 | Yu, Pinhua1,2,3; Huang, Kun1; Zhang, Chao1,2,3; Xie, Keng1,2,3; He, Xiuqiong1,2,3; Liu, Huizhou1 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2011-08-03 |
| 卷号 | 50期号:15页码:9368-9376 |
| 关键词 | AUTOMOTIVE CATALYTIC-CONVERTERS AQUEOUS 2-PHASE SYSTEMS BLOCK-COPOLYMERS GROUP-METALS POLY(ETHYLENE OXIDE) ORGANIC-SOLVENT WATER RECOVERY BEHAVIOR MICELLIZATION |
| ISSN号 | 0888-5885 |
| 通讯作者 | Huang, K |
| 英文摘要 | Three-liquid-phase extraction and one-step separation of platinum, palladium, and rhodium in the system composed of diisoamyl sulphide (S201), polyethylene oxide-polypropylene oxide random block copolymer (EOPO), Na2SO4, and H2O were investigated. Experimental results indicated that phase-forming salt type, salt concentrations, coexisting H+ and Cl- concentrations in equilibrious Na2SO4 aqueous solutions have significant influences on the three-liquid-phase partitioning behaviors of Pt(IV), Pd(II), and Rh(III). Under the optimized operation parameters, over 99 wt % of Pd(II), about 90 wt % of Pt(IV), and 85 wt % of Rh(III) in initial feed solutions were respectively concentrated into S201 top phase, EOPO middle phase, and Na2SO4 bottom aqueous phase. The present work explores a possibility to develop a three-liquid-phase extraction approach for one-step separation of platinum metal ions in highly concentrated acidic chloride media obtained by hydrometallurgical processes. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | AUTOMOTIVE CATALYTIC-CONVERTERS ; AQUEOUS 2-PHASE SYSTEMS ; BLOCK-COPOLYMERS ; GROUP-METALS ; POLY(ETHYLENE OXIDE) ; ORGANIC-SOLVENT ; WATER ; RECOVERY ; BEHAVIOR ; SALT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000293196700058 |
| 公开日期 | 2013-11-01 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4687]  |
| 专题 | 过程工程研究所_生化工程国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Biochem Engn, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Pinhua,Huang, Kun,Zhang, Chao,et al. One-Step Separation of Platinum, Palladium, and Rhodium: A Three-Liquid-Phase Extraction Approach[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2011,50(15):9368-9376. |
| APA | Yu, Pinhua,Huang, Kun,Zhang, Chao,Xie, Keng,He, Xiuqiong,&Liu, Huizhou.(2011).One-Step Separation of Platinum, Palladium, and Rhodium: A Three-Liquid-Phase Extraction Approach.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,50(15),9368-9376. |
| MLA | Yu, Pinhua,et al."One-Step Separation of Platinum, Palladium, and Rhodium: A Three-Liquid-Phase Extraction Approach".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 50.15(2011):9368-9376. |
入库方式： OAI收割
来源：过程工程研究所
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