Separation of acetone, butanol and ethanol (ABE) from dilute aqueous solutions by silicalite-1/PDMS hybrid pervaporation membranes
文献类型：期刊论文
| 作者 | Zhou, Haoli1,2; Su, Yi1; Chen, Xiangrong1; Wan, Yinhua1 |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2011-06-24 |
| 卷号 | 79期号:3页码:375-384 |
| 关键词 | Pervaporation Acetone-butanol-ethanol (ABE) Silicalite-1 Polydimethylsiloxane (PDMS) Hansen solubility parameter |
| ISSN号 | 1383-5866 |
| 通讯作者 | Wan, YH |
| 英文摘要 | To study the effects of different factors on the separation of acetone, butanol, and ethanol (ABE) from ABE-water solutions by pervaporation with silicalite-l/polydimethylsiloxane (PDMS) hybrid membranes, the adsorption of ABE in the silicalite-1 in acetone-butanol-water solution and ethanol-butanol-water solution was firstly investigated and then the separation of ABE from binary aqueous solutions at different feed concentrations and temperatures was examined. Experimental results showed that butanol could be preferentially adsorbed on silicalite-1 and the permeability of acetone through the membrane was the highest, followed by butanol and ethanol, which was not consistent with the predictions based on the experimental results of adsorption and membrane swelling measurement. This could be explained by Hansen solubility parameters for the component and polymer interactions (delta(m,c)) and for the organic solvent and water interactions (delta(w,i)). In the separation of ABE-water solution by the silicalite-1/PDMS hybrid pervaporation membranes, acetone and ethanol could promote ABE transport through membrane and block water permeation, and the membrane performance could be significantly affected by vacuum pressure in the permeate side. (C) 2011 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | VOLATILE ORGANIC-COMPOUNDS ; FILLED PDMS MEMBRANES ; N-BUTANOL ; CLOSTRIDIUM-ACETOBUTYLICUM ; OPERATING-CONDITIONS ; COMPOSITE MEMBRANES ; LIQUID-MIXTURES ; ZEOLITE ; FERMENTATION ; WATER |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000292858500011 |
| 公开日期 | 2013-11-01 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4704]  |
| 专题 | 过程工程研究所_生化工程国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Haoli,Su, Yi,Chen, Xiangrong,et al. Separation of acetone, butanol and ethanol (ABE) from dilute aqueous solutions by silicalite-1/PDMS hybrid pervaporation membranes[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2011,79(3):375-384. |
| APA | Zhou, Haoli,Su, Yi,Chen, Xiangrong,&Wan, Yinhua.(2011).Separation of acetone, butanol and ethanol (ABE) from dilute aqueous solutions by silicalite-1/PDMS hybrid pervaporation membranes.SEPARATION AND PURIFICATION TECHNOLOGY,79(3),375-384. |
| MLA | Zhou, Haoli,et al."Separation of acetone, butanol and ethanol (ABE) from dilute aqueous solutions by silicalite-1/PDMS hybrid pervaporation membranes".SEPARATION AND PURIFICATION TECHNOLOGY 79.3(2011):375-384. |
入库方式： OAI收割
来源：过程工程研究所
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