Low temperature processing of interlayer-free L0.6Sr0.4Co0.2Fe0.8O3-delta cathodes for intermediate temperature solid oxide fuel cells
文献类型：期刊论文
| 作者 | Lei, Ze; Zhu, Qingshan; Zhao, Li |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2006-10-27 |
| 卷号 | 161期号:2页码:1169-1175 |
| 关键词 | solid oxide fuel cells LSCF YSZ cathode solution combustion method |
| ISSN号 | 0378-7753 |
| 其他题名 | J. Power Sources |
| 中文摘要 | Nanocrystalline La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) powder with a specific surface area of 22.9 m(2) g(-1) and an average particle size of 175 nm was prepared by a nitrate-glycine solution combustion method and subsequent ball-milling. The LSCF precalcined at 800 degrees C (LSCF-800) shows very good low-temperature sintering activity, and can well adhere to electrolyte after sintering at 700 degrees C and above. The single cell Ni-YSZfYSZ/LSCF-800 with the cathode sintered at 750 degrees C demonstrates the lowest polarization resistance and good electrical generation performance, but poor cathode microstructure stability. The sintering activity of LSCF cathode can be tailored through the control of the precalcination temperature of the precursor powder. Precalcining of LSCF powder at 900 degrees C (LSCF-900) increases the optimum sintering temperature of the cathode to 850 degrees C and improves the microstructure stability. The cell Ni-YSZ/YSZ/LSCF-900 with this cathode demonstrates excellent generation performances with the maximum power density greater than 1.0 W cm(-2) and the power density of above 0.80 W cm(-2) at 0.7 V under operation at 700 degrees C. Low temperature processing of the interlayer-free LSCF cathode with good microstructure is beneficial to simplifying the cell structure and improving fuel cell performance. (c) 2006 Elsevier B.V. All rights reserved. |
| 英文摘要 | Nanocrystalline La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) powder with a specific surface area of 22.9 m(2) g(-1) and an average particle size of 175 nm was prepared by a nitrate-glycine solution combustion method and subsequent ball-milling. The LSCF precalcined at 800 degrees C (LSCF-800) shows very good low-temperature sintering activity, and can well adhere to electrolyte after sintering at 700 degrees C and above. The single cell Ni-YSZfYSZ/LSCF-800 with the cathode sintered at 750 degrees C demonstrates the lowest polarization resistance and good electrical generation performance, but poor cathode microstructure stability. The sintering activity of LSCF cathode can be tailored through the control of the precalcination temperature of the precursor powder. Precalcining of LSCF powder at 900 degrees C (LSCF-900) increases the optimum sintering temperature of the cathode to 850 degrees C and improves the microstructure stability. The cell Ni-YSZ/YSZ/LSCF-900 with this cathode demonstrates excellent generation performances with the maximum power density greater than 1.0 W cm(-2) and the power density of above 0.80 W cm(-2) at 0.7 V under operation at 700 degrees C. Low temperature processing of the interlayer-free LSCF cathode with good microstructure is beneficial to simplifying the cell structure and improving fuel cell performance. (c) 2006 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Electrochemistry ; Energy & Fuels |
| 研究领域[WOS] | Electrochemistry ; Energy & Fuels |
| 关键词[WOS] | PERFORMANCE ; SOFCS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000241781200052 |
| 公开日期 | 2013-10-24 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4007]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Multiphase React Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lei, Ze,Zhu, Qingshan,Zhao, Li. Low temperature processing of interlayer-free L0.6Sr0.4Co0.2Fe0.8O3-delta cathodes for intermediate temperature solid oxide fuel cells[J]. JOURNAL OF POWER SOURCES,2006,161(2):1169-1175. |
| APA | Lei, Ze,Zhu, Qingshan,&Zhao, Li.(2006).Low temperature processing of interlayer-free L0.6Sr0.4Co0.2Fe0.8O3-delta cathodes for intermediate temperature solid oxide fuel cells.JOURNAL OF POWER SOURCES,161(2),1169-1175. |
| MLA | Lei, Ze,et al."Low temperature processing of interlayer-free L0.6Sr0.4Co0.2Fe0.8O3-delta cathodes for intermediate temperature solid oxide fuel cells".JOURNAL OF POWER SOURCES 161.2(2006):1169-1175. |
入库方式： OAI收割
来源：过程工程研究所
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