Novel organic-inorganic hybrid mesoporous materials for boron adsorption
文献类型：期刊论文
| 作者 | Wang, L; Qi, T; Zhang, Y |
| 刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| 出版日期 | 2006-03-01 |
| 卷号 | 275期号:1-3页码:73-78 |
| 关键词 | organic-inorganic hybrid mesoporous materials boron adsorbent characterization adsorption capacity selectivity |
| ISSN号 | 0927-7757 |
| 其他题名 | Colloid Surf. A-Physicochem. Eng. Asp. |
| 中文摘要 | Amine groups and polyol groups were sequentially grafted on mesoporous SBA-15 and MCM-41 to synthesize novel organic-inorganic hybrid mesoporous materials as boron adsorbents by a two-step post-grafting method. By means of small-angle XRD, N-2 adsorption-desorption, solid-state NMR, Fourier transform infrared (FT-IR) and elemental analysis, the structure and physicochemical properties of the materials were characterized. The behaviors of the resulting adsorbents in adsorption of boron from Solutions were investigated. The results show that the organic functional groups are successfully grafted on the SBA-15 and MCM-41, while the quantity and the distribution of the functional groups are varied due to the different pore properties of the materials. The boron adsorption isotherms of the adsorbents are in pod accordance with the Langmuir equation. The polyol-functionalized SBA-15 was proved to be a promising adsorbent with the high adsorption capacity of boron up to 0.63 mmol/g as well as the high selectivity towards boron. (c) 2005 Elsevier B.V. All rights reserved. |
| 英文摘要 | Amine groups and polyol groups were sequentially grafted on mesoporous SBA-15 and MCM-41 to synthesize novel organic-inorganic hybrid mesoporous materials as boron adsorbents by a two-step post-grafting method. By means of small-angle XRD, N-2 adsorption-desorption, solid-state NMR, Fourier transform infrared (FT-IR) and elemental analysis, the structure and physicochemical properties of the materials were characterized. The behaviors of the resulting adsorbents in adsorption of boron from Solutions were investigated. The results show that the organic functional groups are successfully grafted on the SBA-15 and MCM-41, while the quantity and the distribution of the functional groups are varied due to the different pore properties of the materials. The boron adsorption isotherms of the adsorbents are in pod accordance with the Langmuir equation. The polyol-functionalized SBA-15 was proved to be a promising adsorbent with the high adsorption capacity of boron up to 0.63 mmol/g as well as the high selectivity towards boron. (c) 2005 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | FUNCTIONALIZED SILICA ; METAL IONS ; SBA-15 ; RESINS ; CHROMATOGRAPHY ; NANOPARTICLES ; ADSORBENTS ; SEPARATION ; CHROMATE ; ARSENATE |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000235523100011 |
| 公开日期 | 2013-10-24 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4030]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Lab Green Proc & Engn, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, L,Qi, T,Zhang, Y. Novel organic-inorganic hybrid mesoporous materials for boron adsorption[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2006,275(1-3):73-78. |
| APA | Wang, L,Qi, T,&Zhang, Y.(2006).Novel organic-inorganic hybrid mesoporous materials for boron adsorption.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,275(1-3),73-78. |
| MLA | Wang, L,et al."Novel organic-inorganic hybrid mesoporous materials for boron adsorption".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 275.1-3(2006):73-78. |
入库方式： OAI收割
来源：过程工程研究所
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