Oxidative esterification of methacrolein to methyl methacrylate over supported palladium catalyst
文献类型：期刊论文
| 作者 | Zhao, W; Cheng, WG; Li, ZX; Wang, L; Zhang, XP; Zhang, SJ |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2006-06-01 |
| 卷号 | 17期号:6页码:739-742 |
| 关键词 | oxidative esterification methacrolein methyl methylcralate palladium alumina |
| ISSN号 | 1001-8417 |
| 其他题名 | Chin. Chem. Lett. |
| 中文摘要 | Supported palladium catalysts, which were used in the oxidative esterification of methacrolein to methyl methacrylate, have been prepared with different carriers and Pd precursors. Experimental results revealed that Pd catalysts with gamma-Al2O3 support and Na2PdCl4 precursor showed good performance. Pd catalyst modified with Pb and Mg indicated that Pd-Mg bimetallic catalyst exhibited considerably higher activity and Pd-Pb exhibited both higher activity and selectivity. 92.27% methacrolein conversion and 90.57% methyl methacrylate selectivity were obtained on Pd-Pb-Mg catalyst. |
| 英文摘要 | Supported palladium catalysts, which were used in the oxidative esterification of methacrolein to methyl methacrylate, have been prepared with different carriers and Pd precursors. Experimental results revealed that Pd catalysts with gamma-Al2O3 support and Na2PdCl4 precursor showed good performance. Pd catalyst modified with Pb and Mg indicated that Pd-Mg bimetallic catalyst exhibited considerably higher activity and Pd-Pb exhibited both higher activity and selectivity. 92.27% methacrolein conversion and 90.57% methyl methacrylate selectivity were obtained on Pd-Pb-Mg catalyst. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000238441500010 |
| 公开日期 | 2013-10-24 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4034]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China 2.Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, W,Cheng, WG,Li, ZX,et al. Oxidative esterification of methacrolein to methyl methacrylate over supported palladium catalyst[J]. CHINESE CHEMICAL LETTERS,2006,17(6):739-742. |
| APA | Zhao, W,Cheng, WG,Li, ZX,Wang, L,Zhang, XP,&Zhang, SJ.(2006).Oxidative esterification of methacrolein to methyl methacrylate over supported palladium catalyst.CHINESE CHEMICAL LETTERS,17(6),739-742. |
| MLA | Zhao, W,et al."Oxidative esterification of methacrolein to methyl methacrylate over supported palladium catalyst".CHINESE CHEMICAL LETTERS 17.6(2006):739-742. |
入库方式： OAI收割
来源：过程工程研究所
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