Control of CaCO(3) crystal growth on PDAC/PSS self-assembled multilayers
文献类型：期刊论文
| 作者 | Du, ZW; Hao, JL; Li, HR |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2005-04-14 |
| 卷号 | 63期号:7页码:587-591 |
| 关键词 | self-assembled multilayers calcium carbonate biomimetic biomineralization nacre |
| ISSN号 | 0567-7351 |
| 其他题名 | Acta Chim. Sin. |
| 中文摘要 | Fabrication of biomimetic larminated composite by mimicking the cyclical matrix control process to form the highly structured Mollusca nacre was presented in this paper. (PDAC/PSS)(n) self-assembled multilayers were built-up through alternative adsorption of polycation and polyanion to a substrate as matrices and their chemical structure was characterized by UV-vis absorption spectra. And then the deposition of CaCO(3) took place on the multilayers by dipping them into a supersaturated CaCO(3) solution. The crystals regulated by (PDAC/PSS)(15)PDAC exhibited hexahedral shape and had a size of about 30 similar to 40 mu m after 10 h deposition. Hexagonal CaCO(3) platelet crystals could be observed on (PDAC/PSS)15 with a relative small size of 10 similar to 20 mu m, which is very similar to the crystals existing in natural nacre. Therefore, CaCO(3) crystals with remarkable morphology similarity to natural biornineralization products were obtained in the presence of artificial polyanion. However, X-ray diffraction results indicated that crystal lattice of both the samples was different from any kind of natural nacre. Consequently, it might be supposed that electrostatic effect is one of the key factors in morphology control while the crystal lattice was determined by other factors. Furthermore, end surface SEM image of (PDAC/PSS)(15)-CaCO(3) composite elucidated that alternation of multilayer growth and deposition of inorganic crystals coupled with morphology regulation could form laminated material. |
| 英文摘要 | Fabrication of biomimetic larminated composite by mimicking the cyclical matrix control process to form the highly structured Mollusca nacre was presented in this paper. (PDAC/PSS)(n) self-assembled multilayers were built-up through alternative adsorption of polycation and polyanion to a substrate as matrices and their chemical structure was characterized by UV-vis absorption spectra. And then the deposition of CaCO(3) took place on the multilayers by dipping them into a supersaturated CaCO(3) solution. The crystals regulated by (PDAC/PSS)(15)PDAC exhibited hexahedral shape and had a size of about 30 similar to 40 mu m after 10 h deposition. Hexagonal CaCO(3) platelet crystals could be observed on (PDAC/PSS)15 with a relative small size of 10 similar to 20 mu m, which is very similar to the crystals existing in natural nacre. Therefore, CaCO(3) crystals with remarkable morphology similarity to natural biornineralization products were obtained in the presence of artificial polyanion. However, X-ray diffraction results indicated that crystal lattice of both the samples was different from any kind of natural nacre. Consequently, it might be supposed that electrostatic effect is one of the key factors in morphology control while the crystal lattice was determined by other factors. Furthermore, end surface SEM image of (PDAC/PSS)(15)-CaCO(3) composite elucidated that alternation of multilayer growth and deposition of inorganic crystals coupled with morphology regulation could form laminated material. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | RED ABALONE SHELL |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000228194300007 |
| 公开日期 | 2013-10-25 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4136]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, ZW,Hao, JL,Li, HR. Control of CaCO(3) crystal growth on PDAC/PSS self-assembled multilayers[J]. ACTA CHIMICA SINICA,2005,63(7):587-591. |
| APA | Du, ZW,Hao, JL,&Li, HR.(2005).Control of CaCO(3) crystal growth on PDAC/PSS self-assembled multilayers.ACTA CHIMICA SINICA,63(7),587-591. |
| MLA | Du, ZW,et al."Control of CaCO(3) crystal growth on PDAC/PSS self-assembled multilayers".ACTA CHIMICA SINICA 63.7(2005):587-591. |
入库方式： OAI收割
来源：过程工程研究所
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