Experimental investigation and particle dynamic simulation for synthesizing titania nanoparticles using diffusion flame
文献类型：期刊论文
| 作者 | Hong, RY; Ren, ZQ; Ding, HM; Li, HZ |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2005-04-15 |
| 卷号 | 108期号:3页码:203-212 |
| 关键词 | combustion diffusion flame nanoparticle titania particle dynamics |
| ISSN号 | 1385-8947 |
| 其他题名 | Chem. Eng. J. |
| 中文摘要 | Using titanium tetrachloride (TiCl4) as a precursor, titania (TiO2) nanoparticles were synthesized in the diffusion flame (DF) of air and liquid petrol gas (LPG). The effects of air and LPG flow rates and flow ratio, flame temperature and flame shape on the synthesized titania nanoparticles were investigated. Experimental investigation showed that the mean particle size of TiO2 increased obviously with increasing airflow rate, and not obviously with that of LPG, the mean particle size at optimal experimental condition was less than 20 nm, the rutile fraction in the synthesized powder increased with increasing flame temperature and the particle size was affected by the flame height. A particle-dynamic model, describing the nucleation and coagulation of titania monomers/nanoparticles, was used to account for the experimental results based on the isothermal assumption. Generally speaking, the calculated particle sizes from the particle dynamics were consist with the experimental measurements, especially, when the feed concentration of TiCl4 was low. (c) 2005 Elsevier B.V. All rights reserved. |
| 英文摘要 | Using titanium tetrachloride (TiCl4) as a precursor, titania (TiO2) nanoparticles were synthesized in the diffusion flame (DF) of air and liquid petrol gas (LPG). The effects of air and LPG flow rates and flow ratio, flame temperature and flame shape on the synthesized titania nanoparticles were investigated. Experimental investigation showed that the mean particle size of TiO2 increased obviously with increasing airflow rate, and not obviously with that of LPG, the mean particle size at optimal experimental condition was less than 20 nm, the rutile fraction in the synthesized powder increased with increasing flame temperature and the particle size was affected by the flame height. A particle-dynamic model, describing the nucleation and coagulation of titania monomers/nanoparticles, was used to account for the experimental results based on the isothermal assumption. Generally speaking, the calculated particle sizes from the particle dynamics were consist with the experimental measurements, especially, when the feed concentration of TiCl4 was low. (c) 2005 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Environmental ; Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | AEROSOL ; COAGULATION ; POWDERS ; COALESCENCE ; GROWTH ; TIO2 ; OXIDATION ; SILICA ; SIO2 |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000229174700003 |
| 公开日期 | 2013-10-25 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4159]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Soochow Univ, Dept Chem Engn, Suzhou 215006, Peoples R China 2.Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Multiphase React, Beijing 100080, Peoples R China 4.IBM Corp, HYDA, Rochester, MN 55901 USA |
| 推荐引用方式 GB/T 7714 | Hong, RY,Ren, ZQ,Ding, HM,et al. Experimental investigation and particle dynamic simulation for synthesizing titania nanoparticles using diffusion flame[J]. CHEMICAL ENGINEERING JOURNAL,2005,108(3):203-212. |
| APA | Hong, RY,Ren, ZQ,Ding, HM,&Li, HZ.(2005).Experimental investigation and particle dynamic simulation for synthesizing titania nanoparticles using diffusion flame.CHEMICAL ENGINEERING JOURNAL,108(3),203-212. |
| MLA | Hong, RY,et al."Experimental investigation and particle dynamic simulation for synthesizing titania nanoparticles using diffusion flame".CHEMICAL ENGINEERING JOURNAL 108.3(2005):203-212. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。