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Chinese Academy of Sciences Institutional Repositories Grid
Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands

文献类型:期刊论文

作者Yao, YW; Lin, HX; Sun, XD; Kou, HZ; Cai, Q; Li, HD; Yu, RB; Wang, D
刊名TRANSITION METAL CHEMISTRY
出版日期2005-04-01
卷号30期号:3页码:294-298
关键词one-dimensional chain coordination polymers magnetic-properties acid mononuclear frameworks bonds salts zinc
ISSN号0340-4285
其他题名Transit. Met. Chem.
中文摘要A novel polymeric complex, [Mn(phen)(pdc)](infinity) ( phen 1,10- phenanthroline, H(2)pdc 2,5-pyridinedicarboxylic acid) has been synthesized from the hydrothermal reaction system of H2pdc, phen, MnO2, and H2O. [Mn(phen)(pdc)](infinity) is characteristic of an edge-sharing dinuclear Mn-II structure unit bridged by pdc, leading to a 2-D framework whose stacking is based on weak H-bond interaction. The temperature dependence of the magnetic susceptibility for [Mn(phen)( pdc)](infinity) indicates antiferromagnetic coupling [J= -2.76(4)cm(-1)] between the adjacent paramagnetic Mn-II ions.
英文摘要A novel polymeric complex, [Mn(phen)(pdc)](infinity) ( phen 1,10- phenanthroline, H(2)pdc 2,5-pyridinedicarboxylic acid) has been synthesized from the hydrothermal reaction system of H2pdc, phen, MnO2, and H2O. [Mn(phen)(pdc)](infinity) is characteristic of an edge-sharing dinuclear Mn-II structure unit bridged by pdc, leading to a 2-D framework whose stacking is based on weak H-bond interaction. The temperature dependence of the magnetic susceptibility for [Mn(phen)( pdc)](infinity) indicates antiferromagnetic coupling [J= -2.76(4)cm(-1)] between the adjacent paramagnetic Mn-II ions.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]ONE-DIMENSIONAL CHAIN ; COORDINATION POLYMERS ; MAGNETIC-PROPERTIES ; ACID ; MONONUCLEAR ; FRAMEWORKS ; BONDS ; SALTS ; ZINC
收录类别SCI
原文出处://WOS:000230717500007
语种英语
WOS记录号WOS:000230717500007
公开日期2013-10-25
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/4172]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
2.Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Yao, YW,Lin, HX,Sun, XD,et al. Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands[J]. TRANSITION METAL CHEMISTRY,2005,30(3):294-298.
APA Yao, YW.,Lin, HX.,Sun, XD.,Kou, HZ.,Cai, Q.,...&Wang, D.(2005).Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands.TRANSITION METAL CHEMISTRY,30(3),294-298.
MLA Yao, YW,et al."Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands".TRANSITION METAL CHEMISTRY 30.3(2005):294-298.

入库方式: OAI收割

来源:过程工程研究所

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