Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands
文献类型：期刊论文
| 作者 | Yao, YW; Lin, HX; Sun, XD; Kou, HZ; Cai, Q; Li, HD; Yu, RB; Wang, D |
| 刊名 | TRANSITION METAL CHEMISTRY
 |
| 出版日期 | 2005-04-01 |
| 卷号 | 30期号:3页码:294-298 |
| 关键词 | one-dimensional chain coordination polymers magnetic-properties acid mononuclear frameworks bonds salts zinc |
| ISSN号 | 0340-4285 |
| 其他题名 | Transit. Met. Chem. |
| 中文摘要 | A novel polymeric complex, [Mn(phen)(pdc)](infinity) ( phen 1,10- phenanthroline, H(2)pdc 2,5-pyridinedicarboxylic acid) has been synthesized from the hydrothermal reaction system of H2pdc, phen, MnO2, and H2O. [Mn(phen)(pdc)](infinity) is characteristic of an edge-sharing dinuclear Mn-II structure unit bridged by pdc, leading to a 2-D framework whose stacking is based on weak H-bond interaction. The temperature dependence of the magnetic susceptibility for [Mn(phen)( pdc)](infinity) indicates antiferromagnetic coupling [J= -2.76(4)cm(-1)] between the adjacent paramagnetic Mn-II ions. |
| 英文摘要 | A novel polymeric complex, [Mn(phen)(pdc)](infinity) ( phen 1,10- phenanthroline, H(2)pdc 2,5-pyridinedicarboxylic acid) has been synthesized from the hydrothermal reaction system of H2pdc, phen, MnO2, and H2O. [Mn(phen)(pdc)](infinity) is characteristic of an edge-sharing dinuclear Mn-II structure unit bridged by pdc, leading to a 2-D framework whose stacking is based on weak H-bond interaction. The temperature dependence of the magnetic susceptibility for [Mn(phen)( pdc)](infinity) indicates antiferromagnetic coupling [J= -2.76(4)cm(-1)] between the adjacent paramagnetic Mn-II ions. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ONE-DIMENSIONAL CHAIN ; COORDINATION POLYMERS ; MAGNETIC-PROPERTIES ; ACID ; MONONUCLEAR ; FRAMEWORKS ; BONDS ; SALTS ; ZINC |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000230717500007 |
| 公开日期 | 2013-10-25 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4172]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China 2.Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, YW,Lin, HX,Sun, XD,et al. Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands[J]. TRANSITION METAL CHEMISTRY,2005,30(3):294-298. |
| APA | Yao, YW.,Lin, HX.,Sun, XD.,Kou, HZ.,Cai, Q.,...&Wang, D.(2005).Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands.TRANSITION METAL CHEMISTRY,30(3),294-298. |
| MLA | Yao, YW,et al."Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands".TRANSITION METAL CHEMISTRY 30.3(2005):294-298. |
入库方式： OAI收割
来源：过程工程研究所
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