A novel organically templated hybrid open-framework manganese phosphate-oxalate
文献类型：期刊论文
| 作者 | Yu, RB; Xing, XR; Saito, T; Azuma, M; Takano, M; Wang, D; Chen, YF; Kumada, N; Kinomura, N |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2005-02-01 |
| 卷号 | 7期号:2页码:221-226 |
| 关键词 | hydrothermal synthesis inorganic-organic hybrid material open-framework crystal structure antiferromagnet |
| ISSN号 | 1293-2558 |
| 其他题名 | Solid State Sci. |
| 中文摘要 | A novel hybrid open-framework manganese phosphate-oxalate templated with an organic amine, [CH3NH2CH3][Mn-2(OH2)(HPO4)(C2O4)(1.5)], has been hydrothermally synthesized and structurally characterized. The light pink compound crystallizes in a triclinic system of space group P (1) over bar (No. 2), with lattice parameters a = 8.3014(1) Angstrom, b = 9.740(2) Angstrom, c = 7.744(2) Angstrom, alpha = 102.32(2)degrees, beta = 93.38(2)degrees, gamma = 75.90(1)degrees, V = 572.7(2) Angstrom(3). In this structure, MnO6 octahedra, PO4 tetrahedra and C2O4 groups are linked to give rise to a three-dimensional open framework containing channels with 10-, 8- and 10-membered windows running along the a, b and c axis, respectively. The organic template diethylenetriamine lies disorderedly in the interspace of the channels along the c axis. The compound is an antiferromagnet with a TN = 9 K. (C) 2004 Elsevier SAS. All rights reserved. |
| 英文摘要 | A novel hybrid open-framework manganese phosphate-oxalate templated with an organic amine, [CH3NH2CH3][Mn-2(OH2)(HPO4)(C2O4)(1.5)], has been hydrothermally synthesized and structurally characterized. The light pink compound crystallizes in a triclinic system of space group P (1) over bar (No. 2), with lattice parameters a = 8.3014(1) Angstrom, b = 9.740(2) Angstrom, c = 7.744(2) Angstrom, alpha = 102.32(2)degrees, beta = 93.38(2)degrees, gamma = 75.90(1)degrees, V = 572.7(2) Angstrom(3). In this structure, MnO6 octahedra, PO4 tetrahedra and C2O4 groups are linked to give rise to a three-dimensional open framework containing channels with 10-, 8- and 10-membered windows running along the a, b and c axis, respectively. The organic template diethylenetriamine lies disorderedly in the interspace of the channels along the c axis. The compound is an antiferromagnet with a TN = 9 K. (C) 2004 Elsevier SAS. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear ; Chemistry, Physical ; Physics, Condensed Matter |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | CRYSTAL-STRUCTURE ; STRUCTURAL-CHARACTERIZATION ; MOLECULAR-SIEVE ; COORDINATION FRAMEWORKS ; HYDROTHERMAL SYNTHESIS ; ANION FRAMEWORKS ; IRON PHOSPHATE ; ALUMINOPHOSPHATE ; PHOSPHATOOXALATE ; SPECTROSCOPY |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000227498100010 |
| 公开日期 | 2013-10-25 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4207]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China 2.Yamanashi Univ, Fac Engn, Inst Inorgan Synth, Kofu, Yamanashi 4008511, Japan 3.Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan 4.Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, RB,Xing, XR,Saito, T,et al. A novel organically templated hybrid open-framework manganese phosphate-oxalate[J]. SOLID STATE SCIENCES,2005,7(2):221-226. |
| APA | Yu, RB.,Xing, XR.,Saito, T.,Azuma, M.,Takano, M.,...&Kinomura, N.(2005).A novel organically templated hybrid open-framework manganese phosphate-oxalate.SOLID STATE SCIENCES,7(2),221-226. |
| MLA | Yu, RB,et al."A novel organically templated hybrid open-framework manganese phosphate-oxalate".SOLID STATE SCIENCES 7.2(2005):221-226. |
入库方式： OAI收割
来源：过程工程研究所
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