Selective oxidation of isobutylene over Cs-promoted Mo-Bi-Co-Fe-Ce-O catalyst
文献类型：期刊论文
| 作者 | Wang, L; Li, ZX; Zhang, SJ; Zhang, XP; Zhao, W |
| 刊名 | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| 出版日期 | 2005-10-01 |
| 卷号 | 13期号:5页码:705-708 |
| 关键词 | isobutylene selective oxidation complex catalyst kinetics |
| ISSN号 | 1004-9541 |
| 其他题名 | Chin. J. Chem. Eng. |
| 中文摘要 | Cs-promoted Mo-Bi-Co-Fe-Ce-O catalyst for the selective oxidation of isobutylene to methacrolein had been studied in a fixed bed micro-reactor. The selectivity to methacrolein was significantly improved by the addition of Cs, which could probably enhance the dehydrogenation ability and weaken the oxygenation ability of the catalyst based on temperature programmed reduction (TPR) analysis investigation. The kinetic studies indicated that the oxidation of isobutylene to methacrolein followed the first-order kinetic behavior. |
| 英文摘要 | Cs-promoted Mo-Bi-Co-Fe-Ce-O catalyst for the selective oxidation of isobutylene to methacrolein had been studied in a fixed bed micro-reactor. The selectivity to methacrolein was significantly improved by the addition of Cs, which could probably enhance the dehydrogenation ability and weaken the oxygenation ability of the catalyst based on temperature programmed reduction (TPR) analysis investigation. The kinetic studies indicated that the oxidation of isobutylene to methacrolein followed the first-order kinetic behavior. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | METHACROLEIN ; ISOBUTENE |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000234384000022 |
| 公开日期 | 2013-10-25 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4251]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Res Lab Green Chem & Technol, Inst Proc Engn, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, L,Li, ZX,Zhang, SJ,et al. Selective oxidation of isobutylene over Cs-promoted Mo-Bi-Co-Fe-Ce-O catalyst[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2005,13(5):705-708. |
| APA | Wang, L,Li, ZX,Zhang, SJ,Zhang, XP,&Zhao, W.(2005).Selective oxidation of isobutylene over Cs-promoted Mo-Bi-Co-Fe-Ce-O catalyst.CHINESE JOURNAL OF CHEMICAL ENGINEERING,13(5),705-708. |
| MLA | Wang, L,et al."Selective oxidation of isobutylene over Cs-promoted Mo-Bi-Co-Fe-Ce-O catalyst".CHINESE JOURNAL OF CHEMICAL ENGINEERING 13.5(2005):705-708. |
入库方式： OAI收割
来源：过程工程研究所
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