Synthesis and characterization of micron-sized monodisperse superparamagnetic polymer particles with amino groups
文献类型：期刊论文
| 作者 | Ma, ZY; Guan, YP; Liu, HZ |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2005-08-01 |
| 卷号 | 43期号:15页码:3433-3439 |
| 关键词 | amino group dispersion polymerization monodisperse superparamagnetic polymer particle |
| ISSN号 | 0887-624X |
| 其他题名 | J. Polym. Sci. Pol. Chem. |
| 中文摘要 | Micron-sized monodisperse superparamagnetic polyglycidyl methacrylate (PGMA) particles with functional amino groups were prepared by a process involving: (1) preparation of parent monodisperse PGMA particles by the dispersion polymerization method, (2) chemical modification of the PGMA particles with ethylenediamine (EDA) to yield amino groups, and (3) impregnation of iron ions (Fe2+ and Fe3+) inside the particles and subsequently precipitating them with ammonium hydroxide to form magnetite (Fe3O4) nanoparticles within the polymer particles. The resultant magnetic PGMA particles with amino groups were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), and vibrating sample magnetometry (VSM). SEM showed that the magnetic particles had an average size of 2.6 mu m and were highly monodisperse. TEM demonstrated that the magnetite nanoparticles distributed evenly within the polymer particles. The existence of amino groups in the magnetic polymer particles was confirmed by FTIR. XRD indicated that the magnetic nanoparticles within the polymer were pure Fe3O4 with a spinel structure. VSM results showed that the magnetic polymer particles were superparamagnetic, and saturation magnetization was found to be 16.3 emu/g. The Fe3O4 content of the magnetic particles was 24.3% based on total weight. (c) 2005 Wiley Periodicals, Inc. |
| 英文摘要 | Micron-sized monodisperse superparamagnetic polyglycidyl methacrylate (PGMA) particles with functional amino groups were prepared by a process involving: (1) preparation of parent monodisperse PGMA particles by the dispersion polymerization method, (2) chemical modification of the PGMA particles with ethylenediamine (EDA) to yield amino groups, and (3) impregnation of iron ions (Fe2+ and Fe3+) inside the particles and subsequently precipitating them with ammonium hydroxide to form magnetite (Fe3O4) nanoparticles within the polymer particles. The resultant magnetic PGMA particles with amino groups were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), and vibrating sample magnetometry (VSM). SEM showed that the magnetic particles had an average size of 2.6 mu m and were highly monodisperse. TEM demonstrated that the magnetite nanoparticles distributed evenly within the polymer particles. The existence of amino groups in the magnetic polymer particles was confirmed by FTIR. XRD indicated that the magnetic nanoparticles within the polymer were pure Fe3O4 with a spinel structure. VSM results showed that the magnetic polymer particles were superparamagnetic, and saturation magnetization was found to be 16.3 emu/g. The Fe3O4 content of the magnetic particles was 24.3% based on total weight. (c) 2005 Wiley Periodicals, Inc. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 关键词[WOS] | DISPERSION POLYMERIZATION/ ; SUSPENSION POLYMERIZATION ; MICROSPHERES ; ADSORPTION ; MAGNETITE ; STYRENE ; LATEX ; IMMOBILIZATION ; NANOPARTICLES ; PROTEINS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000230530400022 |
| 公开日期 | 2013-10-25 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4267]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Lab Separat Sci & Engn, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, ZY,Guan, YP,Liu, HZ. Synthesis and characterization of micron-sized monodisperse superparamagnetic polymer particles with amino groups[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2005,43(15):3433-3439. |
| APA | Ma, ZY,Guan, YP,&Liu, HZ.(2005).Synthesis and characterization of micron-sized monodisperse superparamagnetic polymer particles with amino groups.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,43(15),3433-3439. |
| MLA | Ma, ZY,et al."Synthesis and characterization of micron-sized monodisperse superparamagnetic polymer particles with amino groups".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 43.15(2005):3433-3439. |
入库方式： OAI收割
来源：过程工程研究所
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