Synthesis, characterization and catalytic activity of mesoporous Cr-MSU-1
文献类型：期刊论文
| 作者 | Liu, LC; Li, HQ; Cai, WQ; Zhang, Y |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2005-11-01 |
| 卷号 | 21期号:11页码:1311-1314 |
| 关键词 | mesoporous materials Cr-MSU-1 oxidative dehydrogenation ethane carbon dioxide |
| ISSN号 | 1000-6818 |
| 其他题名 | Acta Phys.-Chim. Sin. |
| 中文摘要 | Mesoporous Cr-MSU-1 was successfully prepared by using sodium silicate, chromium nitrate, fatty alcohol polyoxyethylene ether (A(EO)(9)) as the source of silicone, metal and mesostructure-directing agent, respectively. Cr-MSU-1 and MSU-1 were comparatively characterized by XRD, HRTEM, N-2 adsorption-desorption, Fr-IR and DR UV-Vis techniques. No obvious differences on structural and textural properties between them were observed from XRD patterns and N-2 adsorption-desorption isotherms. The HRTEM image confirined that CrMSU-1 took on wormlike mesostructure that was similar to MSU-1. In the Fr-IR patterns, the introduction of Cr showed slight influence to adsorption bands of MSU-1 which indicated that Cr was incorporated into the framework of MSU-1. It is suggested from the DR UV-Vis spectra that Cr species mostly formed Cr(VI) in tetrahedral coordination in Cr-MSU-1. The Cr-MSU-1 catalyst performs well in the dehydrogenation of ethane with CO2 resulting in the production of ethylene with a conversion of 31.7% and a selectivity of 96.1% at 650 degrees C. |
| 英文摘要 | Mesoporous Cr-MSU-1 was successfully prepared by using sodium silicate, chromium nitrate, fatty alcohol polyoxyethylene ether (A(EO)(9)) as the source of silicone, metal and mesostructure-directing agent, respectively. Cr-MSU-1 and MSU-1 were comparatively characterized by XRD, HRTEM, N-2 adsorption-desorption, Fr-IR and DR UV-Vis techniques. No obvious differences on structural and textural properties between them were observed from XRD patterns and N-2 adsorption-desorption isotherms. The HRTEM image confirined that CrMSU-1 took on wormlike mesostructure that was similar to MSU-1. In the Fr-IR patterns, the introduction of Cr showed slight influence to adsorption bands of MSU-1 which indicated that Cr was incorporated into the framework of MSU-1. It is suggested from the DR UV-Vis spectra that Cr species mostly formed Cr(VI) in tetrahedral coordination in Cr-MSU-1. The Cr-MSU-1 catalyst performs well in the dehydrogenation of ethane with CO2 resulting in the production of ethylene with a conversion of 31.7% and a selectivity of 96.1% at 650 degrees C. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | POLYETHYLENE OXIDE SURFACTANT ; MOLECULAR-SIEVES ; SODIUM-SILICATE ; DEHYDROGENATION |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000233313800024 |
| 公开日期 | 2013-10-25 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4273]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, LC,Li, HQ,Cai, WQ,et al. Synthesis, characterization and catalytic activity of mesoporous Cr-MSU-1[J]. ACTA PHYSICO-CHIMICA SINICA,2005,21(11):1311-1314. |
| APA | Liu, LC,Li, HQ,Cai, WQ,&Zhang, Y.(2005).Synthesis, characterization and catalytic activity of mesoporous Cr-MSU-1.ACTA PHYSICO-CHIMICA SINICA,21(11),1311-1314. |
| MLA | Liu, LC,et al."Synthesis, characterization and catalytic activity of mesoporous Cr-MSU-1".ACTA PHYSICO-CHIMICA SINICA 21.11(2005):1311-1314. |
入库方式： OAI收割
来源：过程工程研究所
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