Optical properties of a novel neodymium pentafluoropropionate binuclear complex
文献类型：期刊论文
| 作者 | Gao, Chao1,2; Cui, Kai1; She, Jiangbo1; Hou, Chaoqi1 ; Guo, Hongyan2; Zhao, Wei1; Wei, Wei1,3; Peng, Bo1,3
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| 刊名 | inorganica chimica acta
 |
| 出版日期 | 2009-04-20 |
| 卷号 | 362期号:6页码:2001-2005 |
| 关键词 | Neodymium complex Crystal structure Judd-Ofelt theory Optical property Emission cross-section |
| 合作状况 | 其它 |
| 英文摘要 | a novel neodymium pentafluoropropionate binuclear complex, nd(c(2)f(5)coo)(3)dipy (dipy: 2,2'-dipyridyl), was synthesized and characterized by single-crystal x-ray diffraction. at a concentration of 0.2 m in dmso-d(6), the judd-ofelt parameters (omega(2), omega(4), omega(6)) were calculated from the uv-vis spectrum. according to the small value of omega(2) and the zero splitting energy of (4)f/(3/2) level, a symmetric ligand field of the complex was confirmed in dmso-d(6). strong emission of the complex in dmso-d(6) at 1057 nm with a decay time about 1.3 mu s were detected when excited at 800 nm pumped by a laser diode. the stimulated emission cross-section of (4)f(3/2) -> (4)i(11/2) fluorescence transition was 2.36 x 10 (20) cm(2) and comparable with some laser glasses, which indicated good radiative properties of this neodymium pentafluoropropionate binuclear complex in liquid matrix. (c) 2008 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 激光材料及工作物质 |
| 类目[WOS] | chemistry, inorganic & nuclear |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | nd3+ complexes ; luminescence ; ions ; emission ; photoluminescence ; lanthanides ; intensities ; dmso-d(6) ; magnetism ; spectra |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000265299200050 |
| 公开日期 | 2010-01-13 |
| 源URL | [http://ir.opt.ac.cn/handle/181661/7966]  |
| 专题 | 西安光学精密机械研究所_先进光电与生物材料研发中心 |
| 作者单位 | 1.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Shaanxi, Peoples R China 2.Xian Modern Chem Res Inst, Photoelectron Mat Ctr, Xian 710065, Shaanxi, Peoples R China 3.Fudan Univ, State Key Lab Adv Photon Mat & Devices, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Chao,Cui, Kai,She, Jiangbo,et al. Optical properties of a novel neodymium pentafluoropropionate binuclear complex[J]. inorganica chimica acta,2009,362(6):2001-2005. |
| APA | Gao, Chao.,Cui, Kai.,She, Jiangbo.,Hou, Chaoqi.,Guo, Hongyan.,...&Peng, Bo.(2009).Optical properties of a novel neodymium pentafluoropropionate binuclear complex.inorganica chimica acta,362(6),2001-2005. |
| MLA | Gao, Chao,et al."Optical properties of a novel neodymium pentafluoropropionate binuclear complex".inorganica chimica acta 362.6(2009):2001-2005. |
入库方式： OAI收割
来源：西安光学精密机械研究所
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