Effect of ionic liquid on the oxidative esterification from methacrolein to methyl methacrylate
文献类型：期刊论文
| 作者 | Li, GH; Zhang, SJ; Li, ZX; Li, MX; Zhang, XP |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2004-06-10 |
| 卷号 | 25期号:6页码:1137-1138 |
| 关键词 | ionic liquid methyl methacrylate methacrolein oxidative esterification polymerization inhibitor |
| ISSN号 | 0251-0790 |
| 其他题名 | Chem. J. Chin. Univ.-Chin. |
| 中文摘要 | Ionic liquid(IL), [bmim]PF6, was used in the reaction of one-step oxidative esterification from methacrolein to methyl methacrylate. It was found that ionic liquid not only increased the selectivity of methyl methacrylate but also inhibited its polymerization. The selectivity of methyl methacrylate was increased from 45% to 100% with ionic liquid. The experiment results showed that the content of ionic liquid had no effects on the selectivity of methyl methacrylate in a certain range of IL concentration, which indicated that ionic liquid could be used as a potential inhibitor of polymerization. |
| 英文摘要 | Ionic liquid(IL), [bmim]PF6, was used in the reaction of one-step oxidative esterification from methacrolein to methyl methacrylate. It was found that ionic liquid not only increased the selectivity of methyl methacrylate but also inhibited its polymerization. The selectivity of methyl methacrylate was increased from 45% to 100% with ionic liquid. The experiment results showed that the content of ionic liquid had no effects on the selectivity of methyl methacrylate in a certain range of IL concentration, which indicated that ionic liquid could be used as a potential inhibitor of polymerization. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000222170400037 |
| 公开日期 | 2013-11-05 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/4921]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China 2.Hebei Normal Univ, Coll Chem, Shijiazhuang 050091, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, GH,Zhang, SJ,Li, ZX,et al. Effect of ionic liquid on the oxidative esterification from methacrolein to methyl methacrylate[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(6):1137-1138. |
| APA | Li, GH,Zhang, SJ,Li, ZX,Li, MX,&Zhang, XP.(2004).Effect of ionic liquid on the oxidative esterification from methacrolein to methyl methacrylate.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,25(6),1137-1138. |
| MLA | Li, GH,et al."Effect of ionic liquid on the oxidative esterification from methacrolein to methyl methacrylate".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 25.6(2004):1137-1138. |
入库方式： OAI收割
来源：过程工程研究所
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