Separation of polycyclic aromatic compounds from model gasoline by magnetic alumina sorbent based on pi-complexation
文献类型：期刊论文
| 作者 | Shan, GB; Liu, HZ; Xing, JM; Zhang, GD; Wang, K |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2004-02-04 |
| 卷号 | 43期号:3页码:758-761 |
| 关键词 | adsorption desulfurization halides |
| ISSN号 | 0888-5885 |
| 其他题名 | Ind. Eng. Chem. Res. |
| 中文摘要 | Magnetic alumina sorbent was used in the separation of aromatic compounds from gasoline by a pi-complexation mechanism. Magnetic alumina sorbents can effectively adsorb polycyclic aromatics and polycyclic aromatic sulfur compounds from model gasoline, and the amounts adsorbed were up to 0.12 mmol.(g of sorbent)(-1). The interactions between various aromatics and sorbents of different acidities were studied. The results showed that the amounts adsorbed are related to the capability of forming pi-complexation interactions, and the magnetic alumina sorbent used was found to have the following order of adsorptive ability for aromatics: pyrene > naphthalene > DBT approximate to fluorene. Al3+ and its oxide are Lewis pi-acids, and aromatic compounds are Lewis pi-bases; thus, they can form pi-complexes with each other. The pi-complexation was verified by fluorescence spectrum. The quenching of the fluorescence of pyrene by Al3+ was due to partial pi-electron transfer from pyrene to the cation according to Lewis theory and fluorescence quenching theory. |
| 英文摘要 | Magnetic alumina sorbent was used in the separation of aromatic compounds from gasoline by a pi-complexation mechanism. Magnetic alumina sorbents can effectively adsorb polycyclic aromatics and polycyclic aromatic sulfur compounds from model gasoline, and the amounts adsorbed were up to 0.12 mmol.(g of sorbent)(-1). The interactions between various aromatics and sorbents of different acidities were studied. The results showed that the amounts adsorbed are related to the capability of forming pi-complexation interactions, and the magnetic alumina sorbent used was found to have the following order of adsorptive ability for aromatics: pyrene > naphthalene > DBT approximate to fluorene. Al3+ and its oxide are Lewis pi-acids, and aromatic compounds are Lewis pi-bases; thus, they can form pi-complexes with each other. The pi-complexation was verified by fluorescence spectrum. The quenching of the fluorescence of pyrene by Al3+ was due to partial pi-electron transfer from pyrene to the cation according to Lewis theory and fluorescence quenching theory. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | ADSORPTION ; DESULFURIZATION ; HALIDES |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000188543400013 |
| 公开日期 | 2013-11-05 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5015]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Lab Separat Sci & Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shan, GB,Liu, HZ,Xing, JM,et al. Separation of polycyclic aromatic compounds from model gasoline by magnetic alumina sorbent based on pi-complexation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2004,43(3):758-761. |
| APA | Shan, GB,Liu, HZ,Xing, JM,Zhang, GD,&Wang, K.(2004).Separation of polycyclic aromatic compounds from model gasoline by magnetic alumina sorbent based on pi-complexation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,43(3),758-761. |
| MLA | Shan, GB,et al."Separation of polycyclic aromatic compounds from model gasoline by magnetic alumina sorbent based on pi-complexation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 43.3(2004):758-761. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。