Synthesis and characterization of crosslinked uniform polymeric microspheres containing a polyimide prepolymer by a new emulsification process
文献类型：期刊论文
| 作者 | Ma, GH; Fujiwara, J; Su, ZG; Omi, S |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2003-08-15 |
| 卷号 | 41期号:16页码:2588-2598 |
| 关键词 | emulsification crosslinking particle size distribution polystyrene liquid-crystal display (LCD) |
| ISSN号 | 0887-624X |
| 其他题名 | J. Polym. Sci. Pol. Chem. |
| 中文摘要 | A highly crosslinked poly(styrene-divinyl benzene-trimethyolpropane trimethacrylate) microsphere containing a polyimide prepolymer (PIP) was prepared by a new emulsification method, Shirasu porous glass (SPG) membrane emulsification, and a subsequent radical suspension polymerization. That is, a mixture of styrene, divinyl benzene, trimethyol propane trimethacrylate (TMPTMA), and PIP containing an initiator was permeated through the uniform pores of the SPG membrane into a continuous phase containing a stabilizer to form uniform droplets. Then, the suspension polymerization was carried out at 65 degreesC for 24 h. The trifunctional crosslinker TMPTMA was added to enhance the destructive strength of the microsphere, and PIP was incorporated into the microsphere to provide an adhesion force by a known self-curing reaction at 220 degreesC. The effects of the feed amounts of TMPTMA and PIP on the monomer conversion, size distribution, and destructive strength of the microsphere were investigated. The monomer conversion increased with an increase in TMPTMA. The particle size distribution became narrower as the TMPTMA feed amount increased, but it became broader with an increase in PIP. The destructive strength increased with increases in TMPTMA and PIP. After a heat treatment at 220 degreesC, the destructive strength decreased because of the heat degradation of the polymer. The addition of TMPTMA suppressed the heat degradation, and PIP could undergo self-curing at 220 'C. The obtained highly crosslinked uniform microsphere containing PIP has potential applications in liquid-crystal displays. (C) 2003 Wiley Periodicals, Inc. |
| 英文摘要 | A highly crosslinked poly(styrene-divinyl benzene-trimethyolpropane trimethacrylate) microsphere containing a polyimide prepolymer (PIP) was prepared by a new emulsification method, Shirasu porous glass (SPG) membrane emulsification, and a subsequent radical suspension polymerization. That is, a mixture of styrene, divinyl benzene, trimethyol propane trimethacrylate (TMPTMA), and PIP containing an initiator was permeated through the uniform pores of the SPG membrane into a continuous phase containing a stabilizer to form uniform droplets. Then, the suspension polymerization was carried out at 65 degreesC for 24 h. The trifunctional crosslinker TMPTMA was added to enhance the destructive strength of the microsphere, and PIP was incorporated into the microsphere to provide an adhesion force by a known self-curing reaction at 220 degreesC. The effects of the feed amounts of TMPTMA and PIP on the monomer conversion, size distribution, and destructive strength of the microsphere were investigated. The monomer conversion increased with an increase in TMPTMA. The particle size distribution became narrower as the TMPTMA feed amount increased, but it became broader with an increase in PIP. The destructive strength increased with increases in TMPTMA and PIP. After a heat treatment at 220 degreesC, the destructive strength decreased because of the heat degradation of the polymer. The addition of TMPTMA suppressed the heat degradation, and PIP could undergo self-curing at 220 'C. The obtained highly crosslinked uniform microsphere containing PIP has potential applications in liquid-crystal displays. (C) 2003 Wiley Periodicals, Inc. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 关键词[WOS] | DISPERSION POLYMERIZATION ; POLAR-SOLVENTS ; PARTICLES ; STYRENE |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000184408800016 |
| 公开日期 | 2013-11-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5363]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Nalt Key Lab Biochem Engn, Beijing 100080, Peoples R China 2.Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Tokyo 1848588, Japan |
| 推荐引用方式 GB/T 7714 | Ma, GH,Fujiwara, J,Su, ZG,et al. Synthesis and characterization of crosslinked uniform polymeric microspheres containing a polyimide prepolymer by a new emulsification process[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2003,41(16):2588-2598. |
| APA | Ma, GH,Fujiwara, J,Su, ZG,&Omi, S.(2003).Synthesis and characterization of crosslinked uniform polymeric microspheres containing a polyimide prepolymer by a new emulsification process.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,41(16),2588-2598. |
| MLA | Ma, GH,et al."Synthesis and characterization of crosslinked uniform polymeric microspheres containing a polyimide prepolymer by a new emulsification process".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 41.16(2003):2588-2598. |
入库方式： OAI收割
来源：过程工程研究所
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