Synthesis and characterization of polyurethaneurea-vinyl polymer (PUU-VP) uniform hybrid microspheres by SPG emulsification technique and subsequent suspension polymerization
文献类型：期刊论文
| 作者 | Ma, GH; An, CJ; Yuyama, H; Su, ZG; Omi, S |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2003-07-05 |
| 卷号 | 89期号:1页码:163-178 |
| 关键词 | polyurethanes composites interpenetrating networks (IPN) |
| ISSN号 | 0021-8995 |
| 其他题名 | J. Appl. Polym. Sci. |
| 中文摘要 | Uniform polyurethaneurea-vinyl polymer (PUU-VP) hybrid microspheres of about 20 mum were prepared by a Shirasu porous glass (SPG) membrane emulsification technique and a subsequent radical suspension polymerization process, that is, a mixture of a 40 wt% urethane prepolymer (UP) solution of xylene and a vinyl monomer (VP) containing an initiator was permeated through the uniform pores of the SPG membrane into a continuous phase containing a stabilizer to form uniform droplets. Then, the droplets were allowed to stand for chain extension at room temperature with di- or triamines for 2 h in the absence or presence of ethyl acetate (EA), followed by suspension polymerization at 70degreesC for 24 h. The effect of the type and the amount of the monomer composition, crosslinker, and chain extender on the monomer conversion, particle morphology, and stability of the dispersion was investigated. A strong relationship was found between the compatibility of PUU with VP and the stability of the dispersion. The monomer conversion increased and the stability of the dispersion was improved as the amount of the crosslinker was increased. Solid and spherical PUU-VA hybrid particles with a smooth surface and a higher destructive strength were obtained when a trifunctional crosslinker and a chain extender were used together. (C) 2003 Wiley Periodicals, Inc. |
| 英文摘要 | Uniform polyurethaneurea-vinyl polymer (PUU-VP) hybrid microspheres of about 20 mum were prepared by a Shirasu porous glass (SPG) membrane emulsification technique and a subsequent radical suspension polymerization process, that is, a mixture of a 40 wt% urethane prepolymer (UP) solution of xylene and a vinyl monomer (VP) containing an initiator was permeated through the uniform pores of the SPG membrane into a continuous phase containing a stabilizer to form uniform droplets. Then, the droplets were allowed to stand for chain extension at room temperature with di- or triamines for 2 h in the absence or presence of ethyl acetate (EA), followed by suspension polymerization at 70degreesC for 24 h. The effect of the type and the amount of the monomer composition, crosslinker, and chain extender on the monomer conversion, particle morphology, and stability of the dispersion was investigated. A strong relationship was found between the compatibility of PUU with VP and the stability of the dispersion. The monomer conversion increased and the stability of the dispersion was improved as the amount of the crosslinker was increased. Solid and spherical PUU-VA hybrid particles with a smooth surface and a higher destructive strength were obtained when a trifunctional crosslinker and a chain extender were used together. (C) 2003 Wiley Periodicals, Inc. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 关键词[WOS] | METHACRYLATE) COMPOSITE MICROSPHERES ; EMULSION CAST FILMS ; BISPHENOL-A POLYOL ; PHYSICAL-PROPERTIES ; AQUEOUS DISPERSION ; GLASS MEMBRANE ; PARTICLES ; DMPA ; MORPHOLOGY ; H12MDI |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000182709600020 |
| 公开日期 | 2013-11-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5364]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100080, Peoples R China 2.Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan 3.NIPPON NSC Ltd, Corp Res Div, Osaka 5628586, Japan |
| 推荐引用方式 GB/T 7714 | Ma, GH,An, CJ,Yuyama, H,et al. Synthesis and characterization of polyurethaneurea-vinyl polymer (PUU-VP) uniform hybrid microspheres by SPG emulsification technique and subsequent suspension polymerization[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2003,89(1):163-178. |
| APA | Ma, GH,An, CJ,Yuyama, H,Su, ZG,&Omi, S.(2003).Synthesis and characterization of polyurethaneurea-vinyl polymer (PUU-VP) uniform hybrid microspheres by SPG emulsification technique and subsequent suspension polymerization.JOURNAL OF APPLIED POLYMER SCIENCE,89(1),163-178. |
| MLA | Ma, GH,et al."Synthesis and characterization of polyurethaneurea-vinyl polymer (PUU-VP) uniform hybrid microspheres by SPG emulsification technique and subsequent suspension polymerization".JOURNAL OF APPLIED POLYMER SCIENCE 89.1(2003):163-178. |
入库方式： OAI收割
来源：过程工程研究所
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