Synthesis of functional graft copolymers by solution copolymerization and their evaluation as dispersants in nonaqueous phase dispersion polymerization
文献类型：期刊论文
| 作者 | Fujioka, M; Ma, GH; Du, YZ; Ogino, K; Nagai, M; Omi, S |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2003-06-15 |
| 卷号 | 41期号:12页码:1788-1798 |
| 关键词 | graft copolymers synthesis of dispersants solution polymerization nonaqueous phase dispersion polymerization monodispersed polymer particles macromonomer polystyrene |
| ISSN号 | 0887-624X |
| 其他题名 | J. Polym. Sci. Pol. Chem. |
| 中文摘要 | The poly(HEMA-co-MMA-g-PMMA) graft copolymer was prepared with a poly(methyl methacrylate) (PMMA) macromonomer, 2-hydroxyethyl methacrylate (HEMA), and methyl methacrylate (MMA), and its application as a dispersant for the nonaqueous phase dispersion polymerization of polystyrene (PST) was investigated. Monodisperse PST particles were obtained with two-dimensionally tailored graft copolymers, with the number of grafted chains controlled and the polar component (HEMA) in the backbone chains balanced. As for the reactor, a stirred vessel with moderate agitation yielded uniform polymer particles, whereas sealed glass ampules with an overturning motion yielded broader size distributions. Increasing the polarity of the solvent in the continuous phase yielded smaller polymer particles with a gradual deterioration of monodispersity. Uniform polymer particles with a coefficient of variation of less than 6% were obtained up to 30 wt % solid contents. (C) 2003 Wiley Periodicals, Inc. |
| 英文摘要 | The poly(HEMA-co-MMA-g-PMMA) graft copolymer was prepared with a poly(methyl methacrylate) (PMMA) macromonomer, 2-hydroxyethyl methacrylate (HEMA), and methyl methacrylate (MMA), and its application as a dispersant for the nonaqueous phase dispersion polymerization of polystyrene (PST) was investigated. Monodisperse PST particles were obtained with two-dimensionally tailored graft copolymers, with the number of grafted chains controlled and the polar component (HEMA) in the backbone chains balanced. As for the reactor, a stirred vessel with moderate agitation yielded uniform polymer particles, whereas sealed glass ampules with an overturning motion yielded broader size distributions. Increasing the polarity of the solvent in the continuous phase yielded smaller polymer particles with a gradual deterioration of monodispersity. Uniform polymer particles with a coefficient of variation of less than 6% were obtained up to 30 wt % solid contents. (C) 2003 Wiley Periodicals, Inc. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Polymer Science |
| 研究领域[WOS] | Polymer Science |
| 关键词[WOS] | POLAR-SOLVENTS ; PARTICLE-SIZE ; POLYSTYRENE ; STYRENE ; MICROSPHERES |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000183207200004 |
| 公开日期 | 2013-11-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5366]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100080, Peoples R China 2.Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan 3.Natl Inst Adv Ind Sci & Technol, Inst Biol Resources & Funct, Tsukuba, Ibaraki 3058566, Japan |
| 推荐引用方式 GB/T 7714 | Fujioka, M,Ma, GH,Du, YZ,et al. Synthesis of functional graft copolymers by solution copolymerization and their evaluation as dispersants in nonaqueous phase dispersion polymerization[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2003,41(12):1788-1798. |
| APA | Fujioka, M,Ma, GH,Du, YZ,Ogino, K,Nagai, M,&Omi, S.(2003).Synthesis of functional graft copolymers by solution copolymerization and their evaluation as dispersants in nonaqueous phase dispersion polymerization.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,41(12),1788-1798. |
| MLA | Fujioka, M,et al."Synthesis of functional graft copolymers by solution copolymerization and their evaluation as dispersants in nonaqueous phase dispersion polymerization".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 41.12(2003):1788-1798. |
入库方式： OAI收割
来源：过程工程研究所
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