Preliminary exploration of the reactor configuration for hydroformylation of 1-dodecene catalyzed by water soluble rhodium complex
文献类型：期刊论文
| 作者 | Mao, ZS; Bi, XY; Yu, GZ; Zhang, YQ; Yang, C; Wang, R |
| 刊名 | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| 出版日期 | 2002-02-01 |
| 卷号 | 10期号:1页码:45-51 |
| 关键词 | 1-dodecene biphasic hydroformylation gas-liquid-liquid reactor reaction engineering surface aeration emulsification n/i ratio |
| ISSN号 | 1004-9541 |
| 其他题名 | Chin. J. Chem. Eng. |
| 中文摘要 | Hydroformylation of 1-dodecene was studied in a biphasic system using water-soluble rhodium complex [RhCl(CO)(TPPTS)(2)] as catalyst in the presence of cetyl trimethyl ammonium bromide as surfactant to enhance the reaction rate. Efforts were devoted to improve the performance of hydroformylation by exploring reactor configuration which enhanced the mixing, dispersion and interphase mass transfer. Experiments were carried out in a 0.5 L autoclave at the total pressure of 1.1 MPa and temperature from 363 K to 373 K. Several surface aeration configurations were tested, and higher hydroformylation rate with higher normal/branched aldehyde ratio produced were achieved. The experiences suggest that improved reactor configuration by taking reaction engineering measures is beneficial to better process economy in alkene hydroformylation. |
| 英文摘要 | Hydroformylation of 1-dodecene was studied in a biphasic system using water-soluble rhodium complex [RhCl(CO)(TPPTS)(2)] as catalyst in the presence of cetyl trimethyl ammonium bromide as surfactant to enhance the reaction rate. Efforts were devoted to improve the performance of hydroformylation by exploring reactor configuration which enhanced the mixing, dispersion and interphase mass transfer. Experiments were carried out in a 0.5 L autoclave at the total pressure of 1.1 MPa and temperature from 363 K to 373 K. Several surface aeration configurations were tested, and higher hydroformylation rate with higher normal/branched aldehyde ratio produced were achieved. The experiences suggest that improved reactor configuration by taking reaction engineering measures is beneficial to better process economy in alkene hydroformylation. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000174602500006 |
| 公开日期 | 2013-11-12 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5634]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mao, ZS,Bi, XY,Yu, GZ,et al. Preliminary exploration of the reactor configuration for hydroformylation of 1-dodecene catalyzed by water soluble rhodium complex[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2002,10(1):45-51. |
| APA | Mao, ZS,Bi, XY,Yu, GZ,Zhang, YQ,Yang, C,&Wang, R.(2002).Preliminary exploration of the reactor configuration for hydroformylation of 1-dodecene catalyzed by water soluble rhodium complex.CHINESE JOURNAL OF CHEMICAL ENGINEERING,10(1),45-51. |
| MLA | Mao, ZS,et al."Preliminary exploration of the reactor configuration for hydroformylation of 1-dodecene catalyzed by water soluble rhodium complex".CHINESE JOURNAL OF CHEMICAL ENGINEERING 10.1(2002):45-51. |
入库方式： OAI收割
来源：过程工程研究所
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