Development of a Co-Ni bimetallic aerogel catalyst for hydrogen production via methane oxidative CO2 reforming in a magnetic assisted fluidized bed
文献类型：期刊论文
| 作者 | Chen, Lin1,2; Zhu, Qingshan1; Hao, Zhigang3; Zhang, Tao1; Xie, Zhaohui1 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2010-08-01 |
| 卷号 | 35期号:16页码:8494-8502 |
| 关键词 | Methane Oxy-CO2 reforming Bimetallic aerogel catalyst Magnetic fluidization Hydrogen production |
| ISSN号 | 0360-3199 |
| 通讯作者 | Zhu, QS |
| 英文摘要 | A novel nano-sized Co-Ni bimetallic aerogel catalyst was synthesized via the sol gel process followed by the supercritical drying method. The catalyst exhibited at least 28% higher activity and 15% higher H-2 selectivity than those of a monometallic cobalt aerogel catalyst in methane oxidative CO2 (Oxy-CO2) reforming. Cold-model experiments revealed that channels were alleviated and the agglomerate size was reduced when the catalyst was applied in a magnetic assisted fluidized bed (MAFB). Owing to the improved fluidization quality of the catalyst in the MAFB reactor, CH4 conversion was raised by 12% and 7% as compared with those in the fixed bed reactor and the conventional fluidized bed reactor, respectively. Furthermore, the catalytic performance was quite stable during a 50 h reaction. This stable performance can be illustrated both by the superior catalytic property of the Co-Ni bimetallic aerogel catalyst and the intensified gas solid interaction in the MAFB reactor. Crown Copyright (C) 2010 Published by Elsevier Ltd on behalf of Professor T. Nejat Veziroglu. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
| 研究领域[WOS] | Chemistry ; Electrochemistry ; Energy & Fuels |
| 关键词[WOS] | LAYERED DOUBLE HYDROXIDES ; SYNTHESIS GAS-PRODUCTION ; CARBON-DIOXIDE ; COBALT CATALYSTS ; UNIFIED APPROACH ; MASS-TRANSFER ; SUPPORTED COBALT ; REACTOR ; NICKEL ; HYDRODYNAMICS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000281344000013 |
| 公开日期 | 2013-11-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6108]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.China Natl Bluestar Grp Co Ltd, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Lin,Zhu, Qingshan,Hao, Zhigang,et al. Development of a Co-Ni bimetallic aerogel catalyst for hydrogen production via methane oxidative CO2 reforming in a magnetic assisted fluidized bed[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2010,35(16):8494-8502. |
| APA | Chen, Lin,Zhu, Qingshan,Hao, Zhigang,Zhang, Tao,&Xie, Zhaohui.(2010).Development of a Co-Ni bimetallic aerogel catalyst for hydrogen production via methane oxidative CO2 reforming in a magnetic assisted fluidized bed.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,35(16),8494-8502. |
| MLA | Chen, Lin,et al."Development of a Co-Ni bimetallic aerogel catalyst for hydrogen production via methane oxidative CO2 reforming in a magnetic assisted fluidized bed".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 35.16(2010):8494-8502. |
入库方式： OAI收割
来源：过程工程研究所
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