Hydrogen evolution by photocatalytic decomposition of water under ultraviolet-visible irradiation over K(2)La(2)Ti(3-x)M(x)O(10+delta) perovskite
文献类型：期刊论文
| 作者 | Wang, Bo1; Li, Chunshan1,2; Hirabayashi, Daisuke1; Suzuki, Kenzi1 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2010-04-01 |
| 卷号 | 35期号:8页码:3306-3312 |
| 关键词 | K(2)La(2)Ti(3-x)M(x)O(10+delta) Water splitting Photocatalyst H(2) Na(2)S/Na(2)SO(3) system |
| ISSN号 | 0360-3199 |
| 通讯作者 | Li, CS |
| 英文摘要 | New layered transition metal substituted perovskite-type oxides K(2)La(2)Ti(3-x)M(x)O(10+delta) (M = Fe, Ni, W; delta varies with different M) were synthesized with high-temperature solid state reaction, and characterized with X-ray diffraction (XRD) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS). The photocatalytic activity of these catalysts was studied under ultraviolet and visible light irradiation. The results indicated that substitution of a part of Ti(4+) with Fe(3+) and W(6+) resulted in a marked increase in water splitting activity. The activity of these catalysts for water splitting decreased in the order: Fe(3+) > W(6+) > Ni(2+) >= no substitution. The effect of different amounts of Ti(4+) with Fe(3+) substitution on water splitting was also evaluated. The highest hydrogen evolution was observed for perovskite composition having a Fe:Ti molar ratio of 1:14 (1:12 weight ratio) and this hydrogen evolution was over 4 times higher than the Fe-free K(2)La(2)Ti(3)O(10) composition. Fe was also found to be a promising component for photo activity under visible light irradiation. Finally, the effect of Na(2)S/Na(2)SO(3) system as the sacrificial agent on the photocatalytic activity was also studied. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
| 研究领域[WOS] | Chemistry ; Electrochemistry ; Energy & Fuels |
| 关键词[WOS] | LAYERED PEROVSKITE ; SULFIDE SUSPENSIONS ; UV-IRRADIATION ; LIGHT ; TIO2 ; ENHANCEMENT ; K2LA2TI3O10 ; SRTIO3 ; SERIES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000277463600016 |
| 公开日期 | 2013-11-19 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6173]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Nagoya Univ, EcoTopia Sci Inst, Nagoya, Aichi 4648603, Japan 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Bo,Li, Chunshan,Hirabayashi, Daisuke,et al. Hydrogen evolution by photocatalytic decomposition of water under ultraviolet-visible irradiation over K(2)La(2)Ti(3-x)M(x)O(10+delta) perovskite[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2010,35(8):3306-3312. |
| APA | Wang, Bo,Li, Chunshan,Hirabayashi, Daisuke,&Suzuki, Kenzi.(2010).Hydrogen evolution by photocatalytic decomposition of water under ultraviolet-visible irradiation over K(2)La(2)Ti(3-x)M(x)O(10+delta) perovskite.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,35(8),3306-3312. |
| MLA | Wang, Bo,et al."Hydrogen evolution by photocatalytic decomposition of water under ultraviolet-visible irradiation over K(2)La(2)Ti(3-x)M(x)O(10+delta) perovskite".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 35.8(2010):3306-3312. |
入库方式： OAI收割
来源：过程工程研究所
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