Fe-containing magnetic ionic liquid as an effective catalyst for the glycolysis of poly(ethylene terephthalate)
文献类型：期刊论文
| 作者 | Wang, Hui1; Yan, Ruiyi1,2; Li, Zengxi1; Zhang, Xiangping2; Zhang, Suojiang2 |
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2010-03-31 |
| 卷号 | 11期号:8页码:763-767 |
| 关键词 | Poly(ethylene terephthalate) Magnetic ionic liquid Catalysis Glycolysis Synergic effect |
| ISSN号 | 1566-7367 |
| 通讯作者 | Li, ZX |
| 英文摘要 | The depolymerization of poly(ethylene terephthalate) (PET) in ethylene glycol could be catalyzed by imidazolium-based Fe-containing ionic liquid, 1-butyl-3-methylimidazolium tetrachloroferrate ([bmim]FeCl(4)). This magnetic ionic liquid exhibits higher catalytic activity for the glycolysis of PET, compared with FeCl(3) or ionic liquid, 1-butyl-3-methylimidazolium chloride ([bmim]Cl). Investigation also shows that the onset reaction temperature of the glycolysis process catalyzed by [bmim]FeCl(4) is much lower, being 140 degrees C. The proposed mechanism indicates that the high catalytic activity of [bmim]FeCl(4) is attributed to the synergic effect of its cation and anion. (C) 2010 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | SOFT-DRINK BOTTLES ; PET WASTE ; DEPOLYMERIZATION ; KINETICS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000276785000019 |
| 公开日期 | 2013-11-19 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6178]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Hui,Yan, Ruiyi,Li, Zengxi,et al. Fe-containing magnetic ionic liquid as an effective catalyst for the glycolysis of poly(ethylene terephthalate)[J]. CATALYSIS COMMUNICATIONS,2010,11(8):763-767. |
| APA | Wang, Hui,Yan, Ruiyi,Li, Zengxi,Zhang, Xiangping,&Zhang, Suojiang.(2010).Fe-containing magnetic ionic liquid as an effective catalyst for the glycolysis of poly(ethylene terephthalate).CATALYSIS COMMUNICATIONS,11(8),763-767. |
| MLA | Wang, Hui,et al."Fe-containing magnetic ionic liquid as an effective catalyst for the glycolysis of poly(ethylene terephthalate)".CATALYSIS COMMUNICATIONS 11.8(2010):763-767. |
入库方式： OAI收割
来源：过程工程研究所
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