Atomic force microscopy of photochemistry and the Baeyer-Villiger reaction of 4,4 '-dimethylbenzophenone in the solid state
文献类型：期刊论文
| 作者 | Zeng, QD; Wang, C; Xu, SD; Bai, CL; Li, Y; Yan, XJ |
| 刊名 | APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
 |
| 出版日期 | 2001-08-01 |
| 卷号 | 73期号:2页码:247-250 |
| 关键词 | crystals photodimerization nanostructures afm |
| ISSN号 | 0947-8396 |
| 其他题名 | Appl. Phys. A-Mater. Sci. Process. |
| 中文摘要 | Nanostructures are formed by photodimerization of crystalline 4,4'-dimethylbenzophenone (1) through intermolecular hydrogen abstraction and Baeyer-Villiger reaction of 1 with m-chloroperoxybenzoic acid (MCPBA) (5) in the solid state. Atomic force microscopy (AFM) reveals that the crystal face 001) of 1 during photodimerization exhibits volcanoes, whereas the same face (001) of 1 yields both craters and volcanoes all over the surface from the contact edge of the crystals during the Baeyer-Villiger reaction. All the experimental results are correlated with the bulk crystal structure. Molecular interpretation of the AFM features of 1 is given. |
| 英文摘要 | Nanostructures are formed by photodimerization of crystalline 4,4'-dimethylbenzophenone (1) through intermolecular hydrogen abstraction and Baeyer-Villiger reaction of 1 with m-chloroperoxybenzoic acid (MCPBA) (5) in the solid state. Atomic force microscopy (AFM) reveals that the crystal face 001) of 1 during photodimerization exhibits volcanoes, whereas the same face (001) of 1 yields both craters and volcanoes all over the surface from the contact edge of the crystals during the Baeyer-Villiger reaction. All the experimental results are correlated with the bulk crystal structure. Molecular interpretation of the AFM features of 1 is given. |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| 类目[WOS] | Materials Science, Multidisciplinary ; Physics, Applied |
| 研究领域[WOS] | Materials Science ; Physics |
| 关键词[WOS] | CRYSTALS ; PHOTODIMERIZATION ; NANOSTRUCTURES ; AFM |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000170335700020 |
| 公开日期 | 2013-11-14 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5731]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem Met, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zeng, QD,Wang, C,Xu, SD,et al. Atomic force microscopy of photochemistry and the Baeyer-Villiger reaction of 4,4 '-dimethylbenzophenone in the solid state[J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING,2001,73(2):247-250. |
| APA | Zeng, QD,Wang, C,Xu, SD,Bai, CL,Li, Y,&Yan, XJ.(2001).Atomic force microscopy of photochemistry and the Baeyer-Villiger reaction of 4,4 '-dimethylbenzophenone in the solid state.APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING,73(2),247-250. |
| MLA | Zeng, QD,et al."Atomic force microscopy of photochemistry and the Baeyer-Villiger reaction of 4,4 '-dimethylbenzophenone in the solid state".APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING 73.2(2001):247-250. |
入库方式： OAI收割
来源：过程工程研究所
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