中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials

文献类型:期刊论文

作者Wang, YL; Wu, YJ
刊名SCIENCE IN CHINA SERIES B-CHEMISTRY
出版日期2001-04-01
卷号44期号:2页码:182-190
关键词isokinetic correlation dominant factor electrophilic substitution arylmercurials
ISSN号1006-9291
其他题名Sci. China Ser. B-Chem.
中文摘要Isokinetic relationships of the series of electrophilic substitution reactions of o-substituted phenylmercurials are studied, and the results show, for the first time! that isokinetic correlation analysis can reveal the dominant factor in the system of the reactions. The analysis of S(E)2 of o-substituted phenylmercuric chlorides indicates that the steric effect of o-substituents is the predominant factor when I-2 is used as electrophilic agent, however, the electronic effect of o-substituents would become the predominant factor when HCl is used as the electrophilic agent. In S(E)1 of o-substituted phenylmercuric chlorides, the results of the analysis display that the predominant factor is the field effects of o-substituents. The determination of predominant factors in those reactions would provide further scientific basis for those reaction mechanisms.
英文摘要Isokinetic relationships of the series of electrophilic substitution reactions of o-substituted phenylmercurials are studied, and the results show, for the first time! that isokinetic correlation analysis can reveal the dominant factor in the system of the reactions. The analysis of S(E)2 of o-substituted phenylmercuric chlorides indicates that the steric effect of o-substituents is the predominant factor when I-2 is used as electrophilic agent, however, the electronic effect of o-substituents would become the predominant factor when HCl is used as the electrophilic agent. In S(E)1 of o-substituted phenylmercuric chlorides, the results of the analysis display that the predominant factor is the field effects of o-substituents. The determination of predominant factors in those reactions would provide further scientific basis for those reaction mechanisms.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ARYLMERCURIALS ; DIMERIZATION
收录类别SCI
原文出处://WOS:000168510600008
语种英语
WOS记录号WOS:000168510600008
公开日期2013-11-14
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/5756]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Chem Met, Natl Key Lab Biochem Engn, Beijing 100080, Peoples R China
2.Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
推荐引用方式
GB/T 7714
Wang, YL,Wu, YJ. Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2001,44(2):182-190.
APA Wang, YL,&Wu, YJ.(2001).Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials.SCIENCE IN CHINA SERIES B-CHEMISTRY,44(2),182-190.
MLA Wang, YL,et al."Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials".SCIENCE IN CHINA SERIES B-CHEMISTRY 44.2(2001):182-190.

入库方式: OAI收割

来源:过程工程研究所

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