Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials
文献类型：期刊论文
| 作者 | Wang, YL; Wu, YJ |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 2001-04-01 |
| 卷号 | 44期号:2页码:182-190 |
| 关键词 | isokinetic correlation dominant factor electrophilic substitution arylmercurials |
| ISSN号 | 1006-9291 |
| 其他题名 | Sci. China Ser. B-Chem. |
| 中文摘要 | Isokinetic relationships of the series of electrophilic substitution reactions of o-substituted phenylmercurials are studied, and the results show, for the first time! that isokinetic correlation analysis can reveal the dominant factor in the system of the reactions. The analysis of S(E)2 of o-substituted phenylmercuric chlorides indicates that the steric effect of o-substituents is the predominant factor when I-2 is used as electrophilic agent, however, the electronic effect of o-substituents would become the predominant factor when HCl is used as the electrophilic agent. In S(E)1 of o-substituted phenylmercuric chlorides, the results of the analysis display that the predominant factor is the field effects of o-substituents. The determination of predominant factors in those reactions would provide further scientific basis for those reaction mechanisms. |
| 英文摘要 | Isokinetic relationships of the series of electrophilic substitution reactions of o-substituted phenylmercurials are studied, and the results show, for the first time! that isokinetic correlation analysis can reveal the dominant factor in the system of the reactions. The analysis of S(E)2 of o-substituted phenylmercuric chlorides indicates that the steric effect of o-substituents is the predominant factor when I-2 is used as electrophilic agent, however, the electronic effect of o-substituents would become the predominant factor when HCl is used as the electrophilic agent. In S(E)1 of o-substituted phenylmercuric chlorides, the results of the analysis display that the predominant factor is the field effects of o-substituents. The determination of predominant factors in those reactions would provide further scientific basis for those reaction mechanisms. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ARYLMERCURIALS ; DIMERIZATION |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000168510600008 |
| 公开日期 | 2013-11-14 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5756]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem Met, Natl Key Lab Biochem Engn, Beijing 100080, Peoples R China 2.Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YL,Wu, YJ. Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2001,44(2):182-190. |
| APA | Wang, YL,&Wu, YJ.(2001).Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials.SCIENCE IN CHINA SERIES B-CHEMISTRY,44(2),182-190. |
| MLA | Wang, YL,et al."Isokinetic correlation analysis of the series of electrophilic substitution reactions of o-substituted phenylmercurials".SCIENCE IN CHINA SERIES B-CHEMISTRY 44.2(2001):182-190. |
入库方式： OAI收割
来源：过程工程研究所
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