Global stability analysis and phase equilibrium calculations at high pressures using the enhanced simulated annealing algorithm
文献类型：期刊论文
| 作者 | Zhu, YS; Wen, H; Xu, ZH |
| 刊名 | CHEMICAL ENGINEERING SCIENCE
 |
| 出版日期 | 2000-09-01 |
| 卷号 | 55期号:17页码:3451-3459 |
| 关键词 | Gibbs free energy phase equilibria global optimization SAA TPDF stability analysis |
| ISSN号 | 0009-2509 |
| 其他题名 | Chem. Eng. Sci. |
| 中文摘要 | An enhanced simulated annealing algorithm (SAA) is presented to verify the phase stability analysis and obtain the true solution of the phase equilibrium problem of multi-component systems at high pressures. Using the enhanced SAA, the global stability analysis is checked on the basis of the minimization results of the tangent plane distance functions (TPDF) for the systems where the nonideal phases are described by PR or SRM equations of state. The consequent phase equilibrium calculation is accomplished by the Newton-Raphson method based upon the stability analysis results. The calculation results for three systems including ternary, quaternary, and five-component mixtures that exhibit multiple immiscibility gaps with different charges at elevated pressures state that the combined algorithm can effectively locate the global minima of these systems involving symmetric models, then the final stability analysis implemented is used to ensure the global minimization. In comparison with MULPRG and HOMPEQ developed by Michelsen and Sun and Seider (1995: Fluid phase Equilibrium, 103, 213-249) respectively, the enhanced SAA is slightly slower and provides comparable reliability, but it is self-starting. (C) 2000 Elsevier Science Ltd. All rights reserved. |
| 英文摘要 | An enhanced simulated annealing algorithm (SAA) is presented to verify the phase stability analysis and obtain the true solution of the phase equilibrium problem of multi-component systems at high pressures. Using the enhanced SAA, the global stability analysis is checked on the basis of the minimization results of the tangent plane distance functions (TPDF) for the systems where the nonideal phases are described by PR or SRM equations of state. The consequent phase equilibrium calculation is accomplished by the Newton-Raphson method based upon the stability analysis results. The calculation results for three systems including ternary, quaternary, and five-component mixtures that exhibit multiple immiscibility gaps with different charges at elevated pressures state that the combined algorithm can effectively locate the global minima of these systems involving symmetric models, then the final stability analysis implemented is used to ensure the global minimization. In comparison with MULPRG and HOMPEQ developed by Michelsen and Sun and Seider (1995: Fluid phase Equilibrium, 103, 213-249) respectively, the enhanced SAA is slightly slower and provides comparable reliability, but it is self-starting. (C) 2000 Elsevier Science Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | LIQUID-LIQUID EQUILIBRIUM ; THERMODYNAMIC ENERGY ANALYSIS ; CRITICAL-POINT CALCULATIONS ; ISOTHERMAL FLASH PROBLEM ; REDLICH-KWONG EQUATION ; GIBBS FREE-ENERGY ; CHEMICAL-EQUILIBRIUM ; MULTICOMPONENT MIXTURES ; MULTIPHASE EQUILIBRIA ; RELIABLE PREDICTION |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000087351200011 |
| 公开日期 | 2013-11-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/5953]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | Chinese Acad Sci, Inst Chem Met, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, YS,Wen, H,Xu, ZH. Global stability analysis and phase equilibrium calculations at high pressures using the enhanced simulated annealing algorithm[J]. CHEMICAL ENGINEERING SCIENCE,2000,55(17):3451-3459. |
| APA | Zhu, YS,Wen, H,&Xu, ZH.(2000).Global stability analysis and phase equilibrium calculations at high pressures using the enhanced simulated annealing algorithm.CHEMICAL ENGINEERING SCIENCE,55(17),3451-3459. |
| MLA | Zhu, YS,et al."Global stability analysis and phase equilibrium calculations at high pressures using the enhanced simulated annealing algorithm".CHEMICAL ENGINEERING SCIENCE 55.17(2000):3451-3459. |
入库方式： OAI收割
来源：过程工程研究所
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