Regression analysis for the host-guest interaction of beta-cyclodextrin with mono- and 1,4-disubstituted benzenes
文献类型：期刊论文
| 作者 | Liu, L; Li, WG; Guo, QX |
| 刊名 | JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
 |
| 出版日期 | 1999-08-01 |
| 卷号 | 34期号:4页码:413-419 |
| 关键词 | benzene derivatives beta-cyclodextrin driving force inclusion regression analysis |
| ISSN号 | 0923-0750 |
| 其他题名 | J. Incl. Phenom. Macrocycl. Chem. |
| 中文摘要 | A multiple regression model was generated, which can satisfactorily estimate the association constants (K-a) for the inclusion complexation of beta-cyclodextrin with mono- and 1,4-disubstituted benzenes. It was found that lnK(a) was correlated with the substituent molar refraction (R-m), hydrophobic constant (pi) and Hammett constant sigma) of the guest compounds with a correlation coefficient of 0.95. The main driving forces for beta-cyclodextrin complexation was concluded to consist of van der Waals forces and hydrophobic interactions, while the influence of electronic effects was small. |
| 英文摘要 | A multiple regression model was generated, which can satisfactorily estimate the association constants (K-a) for the inclusion complexation of beta-cyclodextrin with mono- and 1,4-disubstituted benzenes. It was found that lnK(a) was correlated with the substituent molar refraction (R-m), hydrophobic constant (pi) and Hammett constant sigma) of the guest compounds with a correlation coefficient of 0.95. The main driving forces for beta-cyclodextrin complexation was concluded to consist of van der Waals forces and hydrophobic interactions, while the influence of electronic effects was small. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | INCLUSION COMPLEXES ; ALPHA-CYCLODEXTRIN ; DRIVING-FORCE ; AQUEOUS-SOLUTION ; BINDING FORCES ; DERIVATIVES ; THERMODYNAMICS ; ASSOCIATION ; CATALYSIS ; CONSTANTS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000082507900004 |
| 公开日期 | 2013-11-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6047]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Inst Chem Met, Beijing 100080, Peoples R China 3.Lanzhou Univ, Natl Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, L,Li, WG,Guo, QX. Regression analysis for the host-guest interaction of beta-cyclodextrin with mono- and 1,4-disubstituted benzenes[J]. JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY,1999,34(4):413-419. |
| APA | Liu, L,Li, WG,&Guo, QX.(1999).Regression analysis for the host-guest interaction of beta-cyclodextrin with mono- and 1,4-disubstituted benzenes.JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY,34(4),413-419. |
| MLA | Liu, L,et al."Regression analysis for the host-guest interaction of beta-cyclodextrin with mono- and 1,4-disubstituted benzenes".JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY 34.4(1999):413-419. |
入库方式： OAI收割
来源：过程工程研究所
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