Synthesis of symmetrical biaryls via rhodium catalyzed dimerization of arylmercurials and mechanism of the dimerization
文献类型:期刊论文
| 作者 | Wang, YL; Wu, YJ |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
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| 出版日期 | 2000-05-01 |
| 卷号 | 16期号:2页码:131-135 |
| 关键词 | symmetrical biaryls synthesis arylmercurials intermolecular reaction |
| ISSN号 | 1005-9040 |
| 其他题名 | Chem. Res. Chin. Univ. |
| 中文摘要 | A series of symmetrical biaryls was synthesized from arylmercuric chlorides and biarylmercurials in the presence of [ClRh(CO)(2)](2) in hexamethylphosphoramide (HMPA). The mechanism of the [ClRh(CO)(2)](2) catalyzed dimerization of biarylmercurials was studied, and shown to be mainly intermolecular reaction. |
| 英文摘要 | A series of symmetrical biaryls was synthesized from arylmercuric chlorides and biarylmercurials in the presence of [ClRh(CO)(2)](2) in hexamethylphosphoramide (HMPA). The mechanism of the [ClRh(CO)(2)](2) catalyzed dimerization of biarylmercurials was studied, and shown to be mainly intermolecular reaction. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ORGANOMERCURY COMPOUNDS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000087467300007 |
| 公开日期 | 2013-11-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/6095] ![]() |
| 专题 | 过程工程研究所_研究所(批量导入) |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem Met, Natl Key Lab Biochem Engn, Beijing 100080, Peoples R China 2.Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, YL,Wu, YJ. Synthesis of symmetrical biaryls via rhodium catalyzed dimerization of arylmercurials and mechanism of the dimerization[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2000,16(2):131-135. |
| APA | Wang, YL,&Wu, YJ.(2000).Synthesis of symmetrical biaryls via rhodium catalyzed dimerization of arylmercurials and mechanism of the dimerization.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,16(2),131-135. |
| MLA | Wang, YL,et al."Synthesis of symmetrical biaryls via rhodium catalyzed dimerization of arylmercurials and mechanism of the dimerization".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 16.2(2000):131-135. |
入库方式: OAI收割
来源:过程工程研究所
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